Skip to main content
Log in

The rearrangement of the defect structure of magnetite in a vortex magnetic field according to the Mössbauer spectroscopy data

  • Short Communications
  • Published:
Russian Journal of Physical Chemistry A, Focus on Chemistry Aims and scope Submit manuscript

Abstract

The rearrangement of the defect structure of ferrosoferric oxide Fe3O4 (magnetite) was studied by Mössbauer spectroscopy after treatment in a vortex magnetic field. The experimental dependence of the degree of structure imperfection of magnetite s on the duration of treatment in a magnetic field t MF was obtained. The s(t MF)function nonmonotonically oscillated over the range 0–100 s and experienced a relaxation transition to a new constant value, which was larger at t MF ∼ 300 s. The conclusion was drawn that very fast complex processes occurred in the crystal structure in a magnetic field, which caused irreversible changes in the defect structure of magnetite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. F. Kh. Chibirova, Mod. Phys. Lett. B 19(23), 1119 (2005).

    Article  CAS  Google Scholar 

  2. F. Kh. Chibirova, Fiz. Tverd. Tela (St. Petersburg) 43(7), 1291 (2001) [Phys. Solid State 43 (7), 1291 (2001)].

    CAS  Google Scholar 

  3. G. M. Kaleva, E. D. Politova, Yu. E. Roginskaya, and F. Kh. Chibirova, Zh. Fiz. Khim. 66(11), 3052 (1992).

    CAS  Google Scholar 

  4. H. Topsoe, J. A. Dumesic, and M. Boudart, J. Phys. (Paris) 35, 411 (1974).

    Article  Google Scholar 

  5. P. Kofstad, Nonstoichiometry, Diffusion, and Electrical Conductivity in Binary Metal Oxides (Wiley, New York, 1972; Mir, Moscow, 1975).

    Google Scholar 

  6. T. D. Logvinenko and O. P. Shelyakov, in Intensification of Technological Processes in Apparatus with Velocity Layer (Tekhnika, Kiev, 1976) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. Kh. Chibirova.

Additional information

Original Russian Text © F.Kh. Chibirova, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 11, pp. 2187–2189.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chibirova, F.K. The rearrangement of the defect structure of magnetite in a vortex magnetic field according to the Mössbauer spectroscopy data. Russ. J. Phys. Chem. 82, 1969–1971 (2008). https://doi.org/10.1134/S0036024408110320

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024408110320

Keywords

Navigation