Abstract
The degree of the transformation of MoO3 films (d= 8–130 nm) increased as the duration (1–140 min) and temperature (373–573 K) of thermal treatment grew and as the film thickness decreased under atmospheric conditions. The thermal treatment of MoO3 films decreased the optical density at λ = 350 nm and caused the appearance of an absorption maximum at λ = 870 nm. A mechanism of thermal transformations of MoO3 was suggested. The mechanism included the formation of the [(V a)++e] center during the preparation and thermal treatment of MoO3 films and thermal electron transition from the valence band to the [(V a)++e] center level with the formation of the [e(Va)++e] center.
Similar content being viewed by others
References
Yu. D. Tret’yakov, Chemistry of Nonstoichiometric Oxides (Mosk. Gos. Univ., Moscow, 1974) [in Russian].
V. B. Lazarev, V. V. Sobolev, and I. S. Shaplygin, Chemical and Physical Properties of Simple Metal Oxides (Nauka, Moscow, 1983) [in Russian].
A. T. Vas’ko, Electrochemistry of Molybdenum and Tungsten (Naukova Dumka, Kiev, 1977) [in Russian].
A. R. Lusis, Ya. K. Klyavin’, and Ya. Ya. Kleperis, Elektrokhimiya 18(11), 1538 (1982).
Yu. Ya. Gurevich, Solid Electrolytes (Nauka, Moscow, 1986) [in Russian].
A. R. Lusis and Ya. Ya. Kleperis, Elektrokhimiya 28(10), 1450 (1992).
V. N. Vertoprakhov and E. G. Sal’man, Thermally Stimulated Current in Inorganic Materials (Nauka, Novosibirsk, 1979) [in Russian].
A. L. Shkol’nik, Izv. Akad. Nauk SSSR, Ser. Fiz. 31(12), 2030 (1967).
M. R. Tubbs, Br. J. Appl. Phys. 15, 181 (1964).
C. Arnoldussen Thomas, J. Electrochem. Sol.: Solid-State Sci. Technol. 123, 527 (1976).
G. M. Ramans, Structure and Morphology of Amorphous Films of Tungsten and Molybdenum Trioxides (Latv. Gos. Univ. im. P. Stuchki, Riga, 1987) [in Russian].
Maosong Tong and Guorui Dai, J. Mater. Sci. 36, 2535 (2001).
V. N. Andreev and S. E. Nikitin, Fiz. Tverd. Tela (St. Petrsburg) 43(4), 755 (2001) [Phys. Solid State 43 (4), 788 (2001)].
M. Halmann, in Energy Resources through Photochemistry and Catalysis, Ed. by M. Gratzel (Academic, New York, 1983; Mir, Moscow, 1986).
Yu. A. Gruzdkov, E. N. Savinov, and V. N. Parmon, in Photocatalytic Conversion of Solar Energy: Heterogeneous and Homogeneous Molecular Structurally Organized Systems (Nauka, Novosibirsk, 1991), p. 138 [in Russian].
M. A. Porai-Koshits and L. O. Atovmyan, Crystal Chemistry and Stereochemistry of Coordination Compounds of Molybdenum (Nauka, Moscow, 1974) [in Russian].
J. N. Yao, Y. A. Yang, and B. H. Loo, J. Phys. Chem. B 102, 1856 (1998).
I. B. Goncharov and U. F. Fialko, Zh. Fiz. Khim. 76(9), 1610 (2002) [Russ. J. Phys. Chem. 76 (9), 1454 (2002)].
Handbook of Thin Film Technology, Ed. by L. I. Maissel and R. Glang (McGraw-Hill, New York, 1970; Sovetskoe Radio, Moscow, 1977), Vol. 1.
N. V. Borisova, E. P. Surovoi, and I. V. Titov, Materialovedenie, No. 7, 16 (2006).
E. P. Surovoy, N. V. Borisova, and I. V. Titov, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 10, 338 (2006).
N. D. Tomashov, Theory of Corrosion and Protection of Metals (Akad. Nauk SSSR, Moscow, 1960) [in Russian].
J. I. Pankove, Optical Processes in Semiconductors (Prentice-Hall, Englewood Cliffs, NJ, 1971; Mir, Moscow, 1973).
M. M. Gurevich, Photometry (Energoatomizdat, Leningrad, 1983) [in Russian].
M. I. Epshtein, Measurements of Optical Radiation in Electronics (Energoatomizdat, Leningrad, 1990) [in Russian].
A. M. Brodskii and Yu. Ya. Gurevich, Theory of Electron Emission from Metals (Nauka, Moscow, 1973), p. 256 [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.P. Surovoi, N.V. Borisova, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 11, pp. 2120–2125.
Rights and permissions
About this article
Cite this article
Surovoi, E.P., Borisova, N.V. Thermal transformations in nanosized MoO3 layers. Russ. J. Phys. Chem. 82, 1908–1912 (2008). https://doi.org/10.1134/S0036024408110198
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024408110198