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The temperature dependence of saturated vapor pressure over alkaline-earth metal pivaloyltrifluoroacetonate complexes

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The temperature dependences of saturated vapor pressure over M(PTA)2 · 15-crown-5, where M = Ca, Sr, or Ba and PTA is the pivaloyltrifluoroacetonate anion, were studied by the Knudsen effusion method, and the enthalpies of compound sublimation were calculated. Changes in volatility depending on the central metal atom were determined.

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Authors and Affiliations

  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 630600, Russia

    Yu. A. Efimova

  2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhni Novgorod, 603600, Russia

    G. A. Abakumov, B. I. Petrov, T. S. Pochekutova & V. K. Khamylov

Authors
  1. Yu. A. Efimova
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  2. G. A. Abakumov
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  3. B. I. Petrov
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  4. T. S. Pochekutova
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  5. V. K. Khamylov
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Corresponding author

Correspondence to B. I. Petrov.

Additional information

Original Russian Text © Yu.A. Efimova, G.A. Abakumov, B.I. Petrov, T.S. Pochekutova, V.K. Khamylov, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 11, pp. 2007–2010.

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Efimova, Y.A., Abakumov, G.A., Petrov, B.I. et al. The temperature dependence of saturated vapor pressure over alkaline-earth metal pivaloyltrifluoroacetonate complexes. Russ. J. Phys. Chem. 82, 1797–1800 (2008). https://doi.org/10.1134/S0036024408110010

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  • DOI: https://doi.org/10.1134/S0036024408110010

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