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The application of the radioactive tracer technique to study the kinetics of bromide isotope exchange reaction with the participation of strongly basic anion exchange resin indion FF-IP

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Abstract

In the present investigation, the 82Br radioactive isotope was used as a tracer to study the kinetics and mechanism of the exchange reaction between an ion exchange resin and an external solution of bromide ions. In an attempt to study the reversible bromide isotope exchange reaction kinetics, it was expected that whether the initial step was the exchange of radioactive bromide ions from the solution to the ion exchange resin (forward reaction) or from the ion exchange resin to the solution (reverse reaction), the two ion-isotope exchange reactions should occur simultaneously, which was further confirmed by the experimental values of specific reaction rates, 0.142 and 0.141 min−1, respectively. The results will be useful to standardize the process parameters so as to achieve optimum use of ion exchange resins in various industrial applications.

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Authors and Affiliations

  1. Department of Chemistry, University of Mumbai, Santacruz, Mumbai, 400 098, India

    R. S. Lokhande, P. U. Singare & T. S. Prabhavalkar

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  1. R. S. Lokhande
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  2. P. U. Singare
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  3. T. S. Prabhavalkar
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Correspondence to T. S. Prabhavalkar.

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Lokhande, R.S., Singare, P.U. & Prabhavalkar, T.S. The application of the radioactive tracer technique to study the kinetics of bromide isotope exchange reaction with the participation of strongly basic anion exchange resin indion FF-IP. Russ. J. Phys. Chem. 82, 1589–1595 (2008). https://doi.org/10.1134/S0036024408090331

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  • DOI: https://doi.org/10.1134/S0036024408090331

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