Skip to main content
Log in

The low-temperature heat capacity of alkali and alkaline-earth metal uranoborates

  • Chemical Thermodynamics and Thermochemistry
  • Published:
Russian Journal of Physical Chemistry A, Focus on Chemistry Aims and scope Submit manuscript

Abstract

The results of heat capacity measurements for several crystalline uranoborates over the temperature range 0–340 K were discussed and analyzed. Low-temperature heat capacities (T < 50 K) were considered using the Debye theory of the heat capacity of solids and its multifractal generalization. The fractal dimensions of compounds were calculated and the heterodynamic characteristics of their structures determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. N. G. Chernorukov, A. V. Knyazev, N. N. Smirnova, et al., Zh. Fiz. Khim. 80(1), 45 (2006) [Russ. J. Phys. Chem. 80 (1), 37 (2006)].

    Google Scholar 

  2. N. G. Chernorukov, A. V. Knyazev, N. N. Smirnova, et al., Zh. Fiz. Khim. 80(8), 1376 (2006) [Russ. J. Phys. Chem. 80 (8), 1205 (2006)].

    Google Scholar 

  3. N. G. Chernorukov, N. N. Smirnova, A. V. Knyazev, et al., Zh. Fiz. Khim. 81(5), 796 (2007) [Russ. J. Phys. Chem. A 81 (5), 683 (2007)].

    Google Scholar 

  4. N. G. Chernorukov, A. V. Knyazev, N. N. Smirnova, et al., Zh. Fiz. Khim. (in press).

  5. N. V. Karyakin, N. G. Chernorukov, A. V. Knyazev, et al., Radiokhimiya 47(2), 123 (2005) [Radiochemistry 47 (2), 136 (2005)].

    Google Scholar 

  6. O. V. Kortikova, Candidate’s Dissertation in Chemistry (Nizni Novgorod State Univ., Nizhni Novgorod, 2003) [in Russian].

    Google Scholar 

  7. J. J. Katz, G. T. Seaborg, and L. R. Morss, The Chemistry of the Actinide Elements (Chapman and Hall, London, 1986; Mir, Moscow, 1999).

    Google Scholar 

  8. V. V. Tarasov and G. A. Yunitskii, Zh. Fiz. Khim. 39(8), 2077 (1965).

    CAS  Google Scholar 

  9. A. D. Izotov, O. V. Shebershneva, and K. S. Gavrichev, Abstracts of Papers, All-Russian Conference on Thermal Analysis and Calorimetry (Kazan, 1996), pp. 200–202.

  10. V. V. Tarasov, Zh. Fiz. Khim. 24(1), 111 (1950).

    CAS  Google Scholar 

  11. T. S. Yakubov, Dokl. Akad. Nauk SSSR 310(1), 145 (1990).

    Google Scholar 

  12. M. Gasperin, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 46, 372 (1990).

    Article  Google Scholar 

  13. M. Gasperin, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 44, 415 (1988).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. N. Smirnova.

Additional information

Original Russian Text © M.N. Marochkina, N.N. Smirnova, A.V. Knyazev, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 9, pp. 1703–1707.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Marochkina, M.N., Smirnova, N.N. & Knyazev, A.V. The low-temperature heat capacity of alkali and alkaline-earth metal uranoborates. Russ. J. Phys. Chem. 82, 1516–1520 (2008). https://doi.org/10.1134/S0036024408090203

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024408090203

Keywords

Navigation