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The use of recurrent equations in chromatography

  • Presented at the Conference “Chromatography in Chemical Analysis and Physicochemical Investigations”
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Abstract

Recurrent equations A(x + k) = aA(x) + b were shown to be applicable to the approximation not only of virtually arbitrary properties of organic compounds (A) in homologous series (A = n C, k = 1 or 2) but also of the dependences of chromatographic retention parameters on the number of carbon atoms in homologue molecules (A = t R). The same equations described the temperature dependences of retention times of arbitrary compounds under isothermal separation conditions in gas chromatography (x = T, k = ΔT = const) and the dependences of retention times on the concentration of an organic solvent as an eluent component (x = C, k = ΔC = const) under isocratic separation conditions in high performance liquid chromatography.

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Authors and Affiliations

  1. Chemistry Research Institute, St. Petersburg State University, Petrodvorets, 198904, Russia

    I. G. Zenkevich

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  1. I. G. Zenkevich
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Correspondence to I. G. Zenkevich.

Additional information

Original Russian Text © I.G. Zenkevich, 2008, published in Zhurnal Fizicheskoi Khimii, 2008, Vol. 82, No. 6, pp. 1012–1018.

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Zenkevich, I.G. The use of recurrent equations in chromatography. Russ. J. Phys. Chem. 82, 886–892 (2008). https://doi.org/10.1134/S0036024408060022

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