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The thermodynamic characteristics of ion exchange in a sulfonated polymer based on cis-tetraphenylcalix[4]resorcinarene

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The selectivity and thermodynamic characteristics of exchange of protons in SO3H groups of a sulfonated network polymer based on cis-tetraphenylcalix[4]resorcinarene for Na+, Cu2+, and In3+ cations from aqueous solutions are considered. Semiempirical quantum-chemical calculations of molecular ensembles modeling the structure of the elementary polymer unit in the H and Na forms were performed. The experimental data on the equilibrium phase compositions and the heat of exchange were used to calculate the thermodynamic equilibrium constants, Gibbs energy, enthalpy, and entropy of ion exchange.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry and Mechanochemistry (Kemerovo Branch), Siberian Division, Russian Academy of Sciences, Kemerovo, Russia

    G. A. Al’tshuler, L. A. Sapozhnikova, E. V. Ostapova & O. G. Al’tshuler

Authors
  1. G. A. Al’tshuler
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  2. L. A. Sapozhnikova
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  3. E. V. Ostapova
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  4. O. G. Al’tshuler
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Additional information

Original Russian Text © G.N. Al’tshuler. L.A. Sapozhnikova, E.V. Ostapova, O.G. Al’tshuler, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 7, pp. 1159–1164.

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Al’tshuler, G.A., Sapozhnikova, L.A., Ostapova, E.V. et al. The thermodynamic characteristics of ion exchange in a sulfonated polymer based on cis-tetraphenylcalix[4]resorcinarene. Russ. J. Phys. Chem. 81, 1011–1015 (2007). https://doi.org/10.1134/S0036024407070011

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  • DOI: https://doi.org/10.1134/S0036024407070011

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