Skip to main content
Log in

The magnetocaloric effect and heat capacity of ferrimagnetic nanosystems: High-dispersity magnetite

  • Physical Chemistry of Nanoclusters and Nanomaterials
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The magnetocaloric effects of aqueous and ethanolic high-dispersity magnetite suspensions and the magnetite magnetic liquid were determined calorimetrically over the temperature range 15–80°C. The temperature dependence of the magnetocaloric effect of suspensions was evidence of the thermal oxidation of magnetite to maghemite. The temperature dependences of the magnetocaloric effect of the magnetic liquid passed extrema related to the second-order magnetic phase transition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. Ya. Blum, M. M. Maiorov, and A. O. Tsebers, Magnetic Liquids (Zinatne, Riga, 1989) [in Russian].

    Google Scholar 

  2. V. V. Korolev, A. S. Romanov, and I. M. Aref’ev, Zh. Fiz. Khim. 80(3), 548 (2006) [Russ. J. Phys. Chem. 80 (3), 464 (2006)].

    Google Scholar 

  3. V. V. Korolev, A. S. Romanov, and I. M. Aref’ev, Zh. Fiz. Khim. 80(2), 380 (2006) [Russ. J. Phys. Chem. 80 (2), 310 (2006)].

    Google Scholar 

  4. V. V. Korolev, A. E. Zavadskii, V. I. Yashkova, et al., Dokl. Akad. Nauk 361(3), 362 (1998) [Dokl. Chem. Technol. 361Ts–363, 11 (1998)].

    CAS  Google Scholar 

  5. L. A. Shmeleva, L. N. Savina, N. I. Dyupovkin, and V. V. Korolev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 38(6), 71 (1995).

    CAS  Google Scholar 

  6. A. E. Zavadskii, V. V. Korolev, V. I. Yashkova, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 43(5), 124 (2000).

    CAS  Google Scholar 

  7. Chemical Encyclopedia (Bol’shaya Rossiiskaya Entsiklopediya, Moscow, 1992), Vol. 3, p. 765; Vol. 2, p. 254; Vol. 5, p. 86 [in Russian].

  8. K. P. Belov, Usp. Fiz. Nauk 164(6), 603 (1994).

    Article  CAS  Google Scholar 

  9. A. P. Kreshkov, Fundamentals of Analytical Chemistry (Khimiya, Moscow, 1976), Vol. 2, p. 286 [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © V.V. Korolev, I.M. Aref’ev, A.G. Ramazanova, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 6, pp. 1085–1088.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Korolev, V.V., Aref’ev, I.M. & Ramazanova, A.G. The magnetocaloric effect and heat capacity of ferrimagnetic nanosystems: High-dispersity magnetite. Russ. J. Phys. Chem. 81, 949–951 (2007). https://doi.org/10.1134/S0036024407060192

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024407060192

Keywords

Navigation