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The special features of the phase behavior of multicomponent biazeotropic systems

  • Chemical Thermodynamics and Thermochemistry
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Abstract

A mathematical model of vapor-liquid equilibrium was obtained for the benzene-pefluorobenzene-methyl propionate-dimethylsulfoxide system. The phase behavior of the ternary biazeotropic constituent over the sections with a constant dimethylsulfoxide concentration was analyzed. The conditions of separation of the benzene-perfluorobenzene-methyl propionate three-component mixture was predicted. The result was substantiated by extractive rectification calculations in the presence of dimethylsulfoxide.

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Authors and Affiliations

  1. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia

    T. O. Myagkova, T. V. Chelyuskina & A. K. Frolkova

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  1. T. O. Myagkova
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  2. T. V. Chelyuskina
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  3. A. K. Frolkova
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Additional information

Original Russian Text © T.O. Myagkova, T.V. Chelyuskina, A.K. Frolkova, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 6, pp. 971–977.

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Myagkova, T.O., Chelyuskina, T.V. & Frolkova, A.K. The special features of the phase behavior of multicomponent biazeotropic systems. Russ. J. Phys. Chem. 81, 841–846 (2007). https://doi.org/10.1134/S0036024407060027

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  • DOI: https://doi.org/10.1134/S0036024407060027

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