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Kinetics of the adsorption of polystyrene macromolecules from dilute solutions in methyl ethyl ketone on carbon black

  • Physical Chemistry of Surface Phenomena
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Abstract

The kinetics of the adsorption of a mixture of three polystyrenes (the weight-average molecular weight M w = 8300, 34000, and 195000) on nonporous carbon (carbon black pretreated in the argon flow at 3800 K) from dilute solutions in methyl ethyl ketone at 298 K is studied. The kinetic dependences of the adsorption of polystyrenes on carbon black nanoparticles from solutions in methyl ethyl ketone are described by adsorption kinetics equations previously used for describing the adsorption of aromatic hydrocarbons from aqueous solutions by active carbon. The correlation between the kinetic coefficients and the molecular weights of polystyrenes is discussed.

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References

  1. C. Peterson and T. Kwei, J. Phys. Chem. 65, 1331 (1961).

    Google Scholar 

  2. G. Howard and P. M. McConnel, J. Phys. Chem. 71, 2991 (1967).

    Article  CAS  Google Scholar 

  3. Yu. S. Lipatov and L. M. Sergeeva, Adsorption of Polimers (Naukova Dumka, Kiev, 1972) [in Russian].

    Google Scholar 

  4. J. F. Hobben and H. H. Hellinek, J. Polym. Sci. 11, 4 (1953).

    Google Scholar 

  5. E. K. Bogacheva, A. V. Kiselev, Yu. S. Nikitin, and Yu. A. El’tekov, Vysokomol. Soedin., Ser. A 10(3), 375 (1968).

    Google Scholar 

  6. Yu. A. El’tekov, in Surface Phenomena in Polymers, Ed. by Yu. S. Lipatov (Naukova Dumka, Kiev, 1970) [in Russian].

    Google Scholar 

  7. E. S. Baidin, A. S. Nazanskii, M. A. Sukhova, and Yu. A. El’tekov, in Sorption and Chromatography, Ed. by K. V. Chmutov (Nauka, Moscow, 1979) [in Russian].

    Google Scholar 

  8. D. M. Ruthven, Principles of Adsorption and Adsorption Processes (Wiley, New York, 1984), p. 124.

    Google Scholar 

  9. A. E. Rodrigues, J. C. Lopes, Z. P. Lu, et al., J. Chromatogr. 590, 93 (1992).

    Article  CAS  Google Scholar 

  10. D. Sarkar and P. Somssundaran, J. Colloid Interface Sci. 201, 197 (2003).

    Article  Google Scholar 

  11. M. Al-Ghout, M. A. M. Khraishah, M. N. M. Ahmad, and S. Allen, J. Colloid Interface Sci. 287, 6 (2005).

    Article  Google Scholar 

  12. A. M. Stadnik and Yu. A. El’tekov, Zh. Fiz. Khim. 51(1), 228 (1977).

    CAS  Google Scholar 

  13. A. M. Stadnik and Yu. A. El’tekov, Zh. Fiz. Khim. 51(10), 2697 (1977).

    CAS  Google Scholar 

  14. F. Glueckauf, Trans. Faraday Soc. 51, 1540 (1955).

    Article  CAS  Google Scholar 

  15. J. Crank, The Mathematics of Diffusion (Oxford, 1956).

  16. J.-B. Donnet, A. Vidal’, Zh. Vses. Khim. O-va im. D.I. Mendeleeva 31(1), 10 (1986).

    CAS  Google Scholar 

  17. J. Jansen, Rubber Chem. Technol. 55, 669 (1982).

    Google Scholar 

  18. S. V. Orekhov, in Adsorption and Chromatography of Elastomer Macromolecules, Ed. by Yu. A. El’tekov (TsNIITE Neftekhim, Moscow, 1989) [in Russian].

    Google Scholar 

  19. G. Kraus, Reinforcement of Elastomers (Interscience, New York, 1965; Khimiya, Moscow, 1968).

    Google Scholar 

  20. N. A. El’tekova and Yu. A. El’tekov, Zh. Fiz. Khim. 70, 532 (1996) [Russ. J. Phys. Chem. 70, 492 (1996)].

    CAS  Google Scholar 

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Original Russian Text © N.A. El’tekova, Yu.A. El’tekov, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 4, pp. 699–703.

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El’tekova, N.A., El’tekov, Y.A. Kinetics of the adsorption of polystyrene macromolecules from dilute solutions in methyl ethyl ketone on carbon black. Russ. J. Phys. Chem. 81, 602–606 (2007). https://doi.org/10.1134/S0036024407040176

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  • DOI: https://doi.org/10.1134/S0036024407040176

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