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A procedure for including the “crystal effect” in NQR for the example of (Cl3C)3SiCl

  • Structure of Matter and Quantum Chemistry
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Abstract

The 35Cl NQR frequencies of (Cl3C)3SiCl at 77 K are interrelated with the inverse spin-lattice relaxation times. This interrelation is in the general form described by a hyperbola equation. It is shown that the “crystal effect” can be resolved into long-and short-range environment contributions, and the 35Cl NQR frequency for the C-Cl bonds can be extrapolated to the gaseous state.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, GSP-1, 117813, Russia

    G. K. Semin, A. M. Raevskii, S. I. Kuznetsov & E. V. Bryukhova

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  1. G. K. Semin
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  2. A. M. Raevskii
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  3. S. I. Kuznetsov
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  4. E. V. Bryukhova
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Additional information

Original Russian Text © G.K. Semin, A.M. Raevskii, S.I. Kuznetsov, E.V. Bryukhova, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 1, pp. 36–39.

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Semin, G.K., Raevskii, A.M., Kuznetsov, S.I. et al. A procedure for including the “crystal effect” in NQR for the example of (Cl3C)3SiCl. Russ. J. Phys. Chem. 81, 30–33 (2007). https://doi.org/10.1134/S0036024407010086

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  • DOI: https://doi.org/10.1134/S0036024407010086

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