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Critical temperature of capillary condensation in narrow cylindrical pores

  • Physical Chemistry of Surface Phenomena
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Abstract

The dependence of the critical temperature of capillary condensation of an adsorbate in cylindrical pores on the diameter of pores is investigated. The calculation is carried out in the quasi-chemical approximation with a calibration function providing the agreement of results for small pores with exact values obtained by the fragment method. The contribution of the size effect to the calibration function as a function of the diameter of pores is considered in terms of the concept of quasi-one-dimensional behavior of the adsorbate in narrow pores. Various adsorbate-adsorbate potentials are considered.

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Authors and Affiliations

  1. Karpov Research Institute of Physical Chemistry, State Scientific Center of the Russian Federation, ul. Vorontsovo pole 10, Moscow, 105064, Russia

    Yu. K. Tovbin, A. G. Petukhov & D. V. Eremich

Authors
  1. Yu. K. Tovbin
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  2. A. G. Petukhov
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  3. D. V. Eremich
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Additional information

Original Russian Text © Yu.K. Tovbin, A.G. Petukhov, D.V. Eremich, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 12, pp. 2250–2259.

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Tovbin, Y.K., Petukhov, A.G. & Eremich, D.V. Critical temperature of capillary condensation in narrow cylindrical pores. Russ. J. Phys. Chem. 80, 2007–2015 (2006). https://doi.org/10.1134/S0036024406120235

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  • DOI: https://doi.org/10.1134/S0036024406120235

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