Abstract
The distribution of Au(III) between an acid (3 mol/l HCl) aqueous phase and a micellar Triton N-42 solution in n-decane was studied as a function of the concentration of Na2SO4 (0–3.55 mol/l). The high distribution coefficients (200–500) allow 50-fold absolute concentration to be performed at a 90% extraction. Au0 nanoparticles were obtained by the injection solubilization of a reducing agent (hydrazine) into micellar extracts. At low solubilization capacities (≤1 vol %) and high reducing agent concentrations (≥0.2 mol/l) in Triton N-42 micelles, stable systems of Au0 nanoparticles suitable for the spectrophotometric determination of gold were obtained. At high solubilization capacities and low hydrazine concentrations, reduction was accompanied by coagulation and sedimentation processes. These processes were studied by spectrophotometry and the static and dynamic light scattering methods.
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References
C. R. Martin and D. T. Mitchell, Anal. Chem. 70(9), 322 (1998).
V. I. Bukhtiyarov and M. G. Slin’ko, Usp. Khim. 70(2), 167 (2001).
G. B. Sergeev, Usp. Khim. 70(10), 915 (2001).
A. A. Lazarides and G. C. Schatz, J. Phys. Chem. B 104(3), 460 (2000).
Manual on Chemical Analysis of Platinum Metals and Gold Ed. by O. E. Zvyagintsev (Nauka, Moscow, 1965) [in Russian].
C. A. Mirkin, Inorg. Chem. 39(11), 2258 (2000).
V. A. Bogatyrev, L. A. Dykman, Ya. M. Krasnov, et al., Kolloidn. Zh. 64(6), 745 (2002).
G. Schmid and B. Corain, Eur. J. Inorg. Chem., No. 17, 3081 (2003).
B. D. Summ and N. I. Ivanova, Usp. Khim. 69(11), 995 (2000).
A. I. Bulavchenko, V. V. Tatarchuk, O. A. Bulavchenko, and A. T. Arymbaeva, Zh. Neorg. Khim. 50(5), 862 (2005) [Russ. J. Inorg. Chem. 50 (5), 786 (2005)].
M. A. Meretukov, Liquid-Extraction Processes in Nonferrous Metallurgy (Metallurgiya, Moscow, 1985) [in Russian].
R. J. Puddephatt, The Chemistry of Gold (Elsevier, Amsterdam, 1979; Mir, Moscow, 1982) [in Russian].
A. I. Bulavchenko, T. Yu. Podlipskaya, and A. T. Arymbaeva, Zh. Fiz. Khim. 79(5), 904 (2005) [Russ. J. Phys. Chem. 79 (5), 782 (2005)].
A. I. Bulavchenko, E. K. Batishcheva, T. Yu. Podlipskaya, and V. G. Torgov, Kolloidn. Zh. 58(2), 163 (1996) [Colloid J. 58 (2), 153 (1996)].
V. V. Tatarchuk and A. I. Bulavchenko, Zh. Neorg. Khim. 49(8), 1 (2004) [Russ. J. Inorg. Chem. 49 (8), 1225 (2004)].
H. C. van de Hulst, Light Scattering by Small Particles (Wiley, New York, 1957; Inostrannaya Literature, Moscow, 1961).
A. I. Bulavchenko, T. Yu. Podlipskaya, and V. G. Torgov, Zh. Fiz. Khim. 78(12), 2258 (2004) [Russ. J. Phys. Chem. 78 (12), 1999 (2004)].
H. R. Kruyt, Colloid Science (Elsevier, New York, 1952; Inostrannaya Literatura, Moscow, 1955).
G. A. Martynov and R. M. Muller, Dokl. Akad. Nauk SSSR 207(5), 1161 (1972).
S. Clark, P. D. J. Fletcher, and X. Ye, Langmuir 6(7), 1307 (1990).
A. I. Busev and V. M. Ivanov, Analytical Chemistry of Gold (Nauka, Moscow, 1973) [in Russian].
A. I. Bulavchenko, E. K. Batishcheva, T. Yu. Podlipskaya, and V. G. Torgov, Kolloidn. Zh. 60(2), 173 (1998) [Colloid J. 60 (2), 152 (1998)].
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Original Russian Text © A.I. Bulavchenko, A.T. Arymbaeva, O.A. Bulavchenko, V.V. Tatarchuk, N.I. Petrova, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 12, pp. 2220–2225.
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Bulavchenko, A.I., Arymbaeva, A.T., Bulavchenko, O.A. et al. The preparation of gold nanoparticles in triton N-42 reverse micelles after preliminary concentration from acid sulfate-chloride solutions. Russ. J. Phys. Chem. 80, 1980–1985 (2006). https://doi.org/10.1134/S0036024406120181
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DOI: https://doi.org/10.1134/S0036024406120181