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The thermodynamic properties of uranyl metaborate

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The standard enthalpy of formation of crystalline UO2(BO2)2 at 298.15 K was determined by reaction calorimetry (−2542.5 ± 3.5 kJ/mol). The heat capacity of this compound was measured over the temperature range 6–302 K by adiabatic vacuum calorimetry. The thermodynamic functions were calculated, including the standard entropy (502.8 ± 2.1 J/(mol K)) and Gibbs function of formation (−2392.5 ± 4.0 kJ/mol) at 298.15 K. The standard thermodynamic functions of reactions with the participation of uranyl metaborate were determined and analyzed.

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References

  1. I. A. Sobolev, M. I. Ozhovan, T. D. Shcherbatova, and O. G. Batyukhnova, Glasses for Radioactive Waste (Energoatomizdat, Moscow, 1999) [in Russian].

    Google Scholar 

  2. M. Gasperin, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 43, 2031 (1987).

    Article  Google Scholar 

  3. A. A. Nemodruk and Z. K. Karalova, Analytical Chemistry of Boron: 5 B 10.811 (Nauka, Moscow, 1964) [in Russian].

    Google Scholar 

  4. Uranium: Methods of Its Detection (Atomizdat, Moscow, 1964) [in Russian].

  5. S. M. Skuratov, V. P. Kolesov, and A. F. Vorob’ev, Thermochemistry (Mosk. Gos. Univ., Moscow, 1966), Vol. 1 [in Russian].

    Google Scholar 

  6. “Codata Key Values,” J. Chem. Thermodyn. 7(1), 1 (1989).

    Google Scholar 

  7. Thermal Constants of Substances: A Handbook, Ed. by V. P. Glushko (Nauka, Moscow, 1971), Vol. 5 [in Russian].

    Google Scholar 

  8. V. M. Malyshev, G. A. Mil’ner, E. L. Sorkin, and V. F. Shibakin, Prib. Tekh. Eksp. 6, 195 (1985).

    Google Scholar 

  9. N. G. Chernorukov, A. V. Knyazev, I. V. Sergacheva, and A. V. Ershova, Radiokhimiya 46(3), 201 (2004) [Radiochemistry 46 (3), 218 (2004)].

    Google Scholar 

  10. J. J. Katz, G. T. Seaborg, and L. R. Morss, The Chemistry of the Actinide Elements (Chapman and Hall, London, 1986; Mir, Moscow, 1999).

    Google Scholar 

  11. N. V. Karyakin, N. G. Chernorukov, A. V. Knyazev, et al., Radiokhimiya 47(2), 123 (2005) [Radiochemistry 47 (2), 136 (2005)].

    Google Scholar 

  12. N. G. Chernorukov, N. N. Smirnova, A. V. Knyazev, et al., Zh. Fiz. Khim. 80(1), 45 (2006) [Russ. J. Phys. Chem. 80 (1), 37 (2006)].

    Google Scholar 

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Authors and Affiliations

  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    N. G. Chernorukov, N. N. Smirnova, A. V. Knyazev, M. N. Marochkina & A. V. Ershova

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  1. N. G. Chernorukov
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  2. N. N. Smirnova
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  3. A. V. Knyazev
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  4. M. N. Marochkina
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  5. A. V. Ershova
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Original Russian Text © N.G. Chernorukov, N.N. Smirnova, A.V. Knyazev, M.N. Marochkina, A.V. Ershova, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 12, pp. 2153–2157.

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Chernorukov, N.G., Smirnova, N.N., Knyazev, A.V. et al. The thermodynamic properties of uranyl metaborate. Russ. J. Phys. Chem. 80, 1915–1919 (2006). https://doi.org/10.1134/S0036024406120089

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  • DOI: https://doi.org/10.1134/S0036024406120089

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