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The thermodynamic characteristics of hydrogen peroxide in H2SO4-H2O solutions

  • Chemical Thermodynamics and Thermochemistry
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Abstract

The paper presents experimental data and an analysis of literature data on hydrogen peroxide forms in concentrated solutions of sulfuric acid, H2O2(aq), H3O +2 (aq), and HSO −5 (aq). The thermodynamic constants of the parallel equilibria

$$\begin{array}{*{20}c} {H_2 O_2 (aq) + H_3 O^ + (aq) \Leftrightarrow H_3 O_2^ + (aq) + H_2 O (K_1 (298) = 8 \times 10^{ - 4} ),} \\ {H_2 O_2 (aq) + HSO_4^ - (aq) \Leftrightarrow HSO_5^ - (aq) + H_2 O (K_2 (298) = 1.2 \times 10^{ - 2} )} \\ \end{array} $$

were determined. The activity coefficients of H2O2 and Henry constants for solutions of H2O2 in sulfuric acid were calculated.

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Authors and Affiliations

  1. Institute of Energy Problems of Chemical Physics, Leninskii pr. 38/2, Moscow, 117829, Russia

    A. N. Ermakov & I. K. Larin

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 117977, Russia

    Yu. N. Kozlov & A. P. Purmal’

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  1. A. N. Ermakov
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  2. I. K. Larin
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  3. Yu. N. Kozlov
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  4. A. P. Purmal’
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Original Russian Text © A.N. Ermakov, I.K. Larin, Yu.N. Kozlov, A.P. Purmal’, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 12, pp. 2132–2138.

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Ermakov, A.N., Larin, I.K., Kozlov, Y.N. et al. The thermodynamic characteristics of hydrogen peroxide in H2SO4-H2O solutions. Russ. J. Phys. Chem. 80, 1895–1901 (2006). https://doi.org/10.1134/S0036024406120041

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  • DOI: https://doi.org/10.1134/S0036024406120041

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