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Mechanism of solvophobic interactions

  • Proceedings of the All-Russia Seminar on the Structure of Liquids and Solutions
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Abstract

A mechanism of solvophobic interactions based on the concept that the elastic spatial hydrogen-bond network forces out dissolved solvophobic species or the solvophobic moiety of molecules and causes them to aggregate was proposed. The elasticity of the spatial network was estimated based on the isothermal compressibility, compression modulus, and instantaneous shear modulus (a quantity that characterizes structural relaxation). It was concluded that the elasticity of the spatial hydrogen-bond network is the driving force of solvophobic interactions.

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References

  1. W. Kauzmann, Adv. Protein Chem. 14, 1 (1959).

    CAS  Google Scholar 

  2. P. L. Privalov, Biofizika 32(5), 742 (1987).

    CAS  Google Scholar 

  3. S. Tanford, The Hydrophobia Effect: Formation of Micelles and Biological Membranes, 2nd ed. (Wiley, New York, 1980).

    Google Scholar 

  4. A. Ben-Naim and Y. Marcus, J. Chem. Phys. 81, 2016 (1984).

    Article  CAS  Google Scholar 

  5. P. L. Privalov and S. J. Gill, Adv. Protein Chem. 39, 191 (1988).

    Article  CAS  Google Scholar 

  6. H. Ashbaugh, T. Truskett, and P. C. Debenedetti, J. Chem. Phys. 116(7), 2907 (2002).

    Article  CAS  Google Scholar 

  7. G. Hummer, S. Garde, A. E. Garcia, and L. R. Pratt, Chem. Phys. 258, 349 (2000).

    Article  CAS  Google Scholar 

  8. F. Franks, Water: A Comprehensive Tretise 4, 1 (1974).

    Google Scholar 

  9. D. Paschek, Cond. Mat. 0402202 1, 1 (2004).

    Google Scholar 

  10. G. G. Malenkov, Zh. Strukt. Khim. 7(3), 331 (1966).

    CAS  Google Scholar 

  11. M. N. Rodnikova, Zh. Fiz. Khim. 67(2), 275 (1993).

    CAS  Google Scholar 

  12. N. A. Chumaevskii and M. N. Rodnikova, Dokl. Akad. Nauk 364(5), 640 (1999) [Dokl. Phys. Chem. 364 (4–6), 45 (1999)].

    CAS  Google Scholar 

  13. N. A. Chumaevskii and M. N. Rodnikova, J. Mol. Liq. 106(2–3), 167 (2003).

    Article  CAS  Google Scholar 

  14. N. A. Chumaevskii, M. N. Rodnikova, and D. A. Sirotkin, Zh. Neorg. Khim. 50, 634 (2005) [Russ. J. Inorg. Chem. 50, 634 (2005)].

    Google Scholar 

  15. I. Z. Fisher, Statistical Theory of Liquids (Izd. Fiz.-Mat. Lit., Moscow, 1961) [in Russian].

    Google Scholar 

  16. M. N. Rodnikova, T. M. Val’kovskaya, V. N. Kartsev, and D. B. Kayumova, Zh. Fiz. Khim. 77(10), 1917 (2003) [Russ. J. Phys. Chem. 77 (10), 1725 (2003)].

    CAS  Google Scholar 

  17. M. N. Rodnikova, T. M. Val’kovskaya, V. H. Kartzev, and D. B. Kayumova, J. Mol. Liq. 106(2–3), 219 (2003).

    Article  CAS  Google Scholar 

  18. M. N. Rodnikova, in Contemporary Problems of General and Inorganic Chemistry (Inst. Obshch. Neorg. Khim., Ross. Akad. Nauk, Moscow, 2004), p. 276 [in Russian].

    Google Scholar 

  19. Yu. P. Syrnikov, in Solutions: Electrolyte Systems (Ivanovsk. Khim.-Tekhnol. Inst., Ivanovo, 1988), p. 10 [in Russian].

    Google Scholar 

  20. G. M. Zaslavskii, Stochasticity of Dynamic Systems (Nauka, Moscow, 1984) [in Russian].

    Google Scholar 

  21. E. Soctkiewicz, S. Ernst, and J. Glinski, Austica 53, 37 (1983).

    Google Scholar 

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    M. N. Rodnikova

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  1. M. N. Rodnikova
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Original Russian Text © M.N. Rodnikova, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 10, pp. 1806–1808.

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Rodnikova, M.N. Mechanism of solvophobic interactions. Russ. J. Phys. Chem. 80, 1605–1607 (2006). https://doi.org/10.1134/S0036024406100098

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  • DOI: https://doi.org/10.1134/S0036024406100098

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