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The rotational mobility of fulleropyrrolineoxyl in toluene solution

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Abstract

The rotational mobility of a stable fullerene-based nitroxyl radical (fulleropyrrolineoxyl) in toluene was studied. The rotational correlation time of fulleropyrrolineoxyl was found to be about eight times longer than that of 4-oxy-2,2,6,6-tetramethylpiperidine-1-oxyl. The activation energy of the rotational motion of both probes was determined and their hydrodynamic radii estimated.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119899, Russia

    D. A. Chernova & A. Kh. Vorob’ev

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  1. D. A. Chernova
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  2. A. Kh. Vorob’ev
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Original Russian Text © D.A. Chernova, A.Kh. Vorob’ev, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 4, pp. 673–676.

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Chernova, D.A., Vorob’ev, A.K. The rotational mobility of fulleropyrrolineoxyl in toluene solution. Russ. J. Phys. Chem. 80, 575–578 (2006). https://doi.org/10.1134/S0036024406040169

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  • DOI: https://doi.org/10.1134/S0036024406040169

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