Skip to main content
Log in

“Dead zone” in a porous catalyst granule for a nonstationary parallel reaction

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry Aims and scope Submit manuscript

Abstract

The quasi-homogeneous model was used to study the “dead zone” in porous catalyst granules of spherical, cylindrical, and platelike shapes for parallel catalytic reaction with the Langmuir-Hinshelwood kinetics that occur under transient or artificially created nonstationary conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. W. Thiele, Ind. Eng. Chem. 31(7), 916 (1939).

    Article  CAS  Google Scholar 

  2. A. Wheeler, Adv. Catal. 3, 250 (1951).

    Google Scholar 

  3. M. I. Temkin, Kinet. Katal. 16(2), 504 (1975).

    CAS  Google Scholar 

  4. M. I. Temkin, Kinet. Katal. 22(4), 1072 (1981).

    CAS  Google Scholar 

  5. M. I. Temkin, Kinet. Katal. 24(5), 1270 (1983).

    CAS  Google Scholar 

  6. D. A. Frank-Kamenetskii, Diffusion and Heat Transport in Chemical Kinetics (Nauka, Moscow, 1987).

    Google Scholar 

  7. V. V. Andreev and N. I. Kol’tsov, Dokl. Ross. Akad. Nauk 332(5), 581 (1993).

    CAS  Google Scholar 

  8. V. V. Andreev, N. I. Kol’tsov, and V. I. Vozyakov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 36(11), 61 (1993).

    CAS  Google Scholar 

  9. C. N. Satterfield and T. K. Sherwood, The Role of Diffusion in Catalysis (Addison-Westley, London, 1963).

    Google Scholar 

  10. R. Aris, The Mathematical Theory of Diffusion and Reactions in Permeable Catalysis (Clarendon, Oxford, 1975), Vol. 1.

    Google Scholar 

  11. O. A. Malinovskaya, V. S. Beskov, and M. G. Slin’ko, Modeling of Catalytic Processes on Porous Granules (Nauka, Novosibirsk, 1975).

    Google Scholar 

  12. Yu. Sh. Matros, Non-Stationary Processes in Chemical Reactors (Nauka, Novosibirsk, 1982).

    Google Scholar 

  13. V. V. Andreev, Mendeleev Commun., p. 35 (1997).

  14. V. V. Andreev and V. I. Gritsai, Matematicheskoe Modelirovanie 17(6), 3 (2005).

    Google Scholar 

  15. V. V. Andreev, B. V. Alekseev, and N. I. Kol’tsov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 35(11–12), 52 (1992).

    CAS  Google Scholar 

  16. V. V. Andreev, Doctoral Dissertation in Physics and Mathematics (Cheboksary, 1994).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © V.V. Andreev, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 4, pp. 628–633.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Andreev, V.V. “Dead zone” in a porous catalyst granule for a nonstationary parallel reaction. Russ. J. Phys. Chem. 80, 535–540 (2006). https://doi.org/10.1134/S003602440604008X

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602440604008X

Keywords

Navigation