Abstract
The available experimental data on proton affinity were used to calculate the hydrogen affinity (HA) of oxygen-containing molybdenum clusters. As the HA increases, the direct incorporation of the ion into a C-H bond of a hydrocarbon molecule gives way to the direct abstraction of the hydrogen atom accompanied by charge transfer to the organic fragment.
This is a preview of subscription content, log in via an institution to check access.
References
R. Walder and J. L. Franklin, Int. J. Mass Spectrom. Ion Phys. 36, 85 (1980).
V. B. Goncharov and E. F. Fialko, Zh. Fiz. Khim. 74, 681 (2000) [Russ. J. Phys. Chem. 74, 791 (2000)].
V. B. Goncharov and E. F. Fialko, Zh. Strukt. Khim. 43(5), 838 (2002).
L. P. Kazanskii, Dokl. Akad. Nauk SSSR 209, 141 (1973).
K. Eller and H. Schwarz, Chem. Rev. 91, 1121 (1991).
V. B. Goncharov, Kinet. Katal. 45, 498 (2004) [Kinet. Catal. 45, 467 (2004)].
V. B. Goncharov and E. F. Fialko, Zh. Fiz. Khim. 75, 854 (2001) [Russ. J. Phys. Chem. 75, 760 (2001)].
V. B. Goncharov, Kinet. Katal. 44, 548 (2003) [Kinet. Catal. 44, 499(2003)].
V. B. Goncharov, Zh. Fiz. Khim. 78, 1798 (2004) [Russ. J. Phys. Chem. 78, 1560 (2004)].
L. V. Gurvich, G. V. Karachevtsev, V. N. Kondrat’ev, et al., Energies of Chemical Bonds, Ionization Potentials, and Electron Affinities, Ed. by V. N. Kondrat’ev (Nauka, Moscow, 1974) [in Russian].
Author information
Authors and Affiliations
Additional information
Original Russian Text © V.B. Goncharov, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 3, pp. 571–573.
Rights and permissions
About this article
Cite this article
Goncharov, V.B. Reactivity and hydrogen affinity of charged molybdenum oxoclusters in the gas phase. Russ. J. Phys. Chem. 80, 486–488 (2006). https://doi.org/10.1134/S0036024406030320
Received:
Issue Date:
DOI: https://doi.org/10.1134/S0036024406030320