Skip to main content
SpringerLink
Log in

Isotherms of adsorption of aromatic compounds on cellulose from heptane-isopropanol solutions

  • Physical Chemistry of Surface Phenomena
  • Published:
Russian Journal of Physical Chemistry Aims and scope Submit manuscript

Abstract

The isotherms of adsorption of benzene, anisole, benzyl alcohol, and benzaldehyde on the surface of microspherical mesoporous crosslinked cellulose were calculated from the chromatographic peaks of these compounds with consideration given to the longitudinal smearing of the analyte zone under the action of adsorption forces. The solvents were n-heptane-isopropanol mixtures containing various amounts of isopropanol (up to 2 vol %). The adsorption isotherms were described using equations of the displacement adsorption theory. The mechanism of the sorption of aromatic compounds and the physical meaning of the constants entering into the adsorption isotherm equation were discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. J. P. Martin and R. L. Singe, Biochem. J. 35, 1358 (1941).

    CAS  Google Scholar 

  2. I. M. Hais, and K. Macek, Handbuch der Papierchromatographie (G. Fischer, Jena, 1958–1960; Insotrannaya Literature, Moscow, 1962).

    Google Scholar 

  3. J. Porath and P. Flodin, Nature (London) 183, 1657 (1959).

    CAS  Google Scholar 

  4. J. Porath and P. Flodin, Nature (London) 188, 493 (1960).

    Google Scholar 

  5. S. Hjerten, Biochem. Biophys. Acta 79, 393 (1964).

    CAS  Google Scholar 

  6. Yu. I. Khol’kin, Chromatography in Wood Chemistry (Lesnaya Promyshlennost’, Moscow, 1968) [in Russian].

    Google Scholar 

  7. S. A. Kibardin and V. B. Lazurkina, Usp. Khim. 38, 2279 (1969).

    CAS  Google Scholar 

  8. Quantitative Paper and Thin-Layer Chromatography, Ed. by E. J. Shellard (Academic, London, 1968; Mir, Moscow, 1971).

    Google Scholar 

  9. J. Porath, J. Chromatogr. 60, 167 (1971).

    Article  CAS  Google Scholar 

  10. J. R. Benson and D. J. Wov, J. Chromatogr. Sci. 22, 386 (1984).

    CAS  Google Scholar 

  11. G. M. Dorris and D. C. Gray, J. Colloid Interface Sci. 71, 21 (1980).

    Google Scholar 

  12. J. Peska, J. Stamberg, and Z. Blace, Czech Patent No. 172640 (1976).

  13. J. Peska, J. Stamberg, I. Hradil, and M. Ilavsky, J. Chromatogr. 125, 455 (1978).

    Google Scholar 

  14. L. I. Dernovaya and Yu. A. Eltekov, J. Chromatogr. 455, 263 (1988).

    Article  CAS  Google Scholar 

  15. L. I. Dernovaya and Yu. A. El’tekov, Zh. Fiz. Khim. 62, 1843 (1988).

    CAS  Google Scholar 

  16. L. I. Dernovaya and Yu. A. El’tekov, Zh. Fiz. Khim. 70, 728 (1996) [Russ. J. Phys. Chem. 70, 677 (1996)].

    CAS  Google Scholar 

  17. L. I. Dernovaya, Yu. A. Eltekov, J. Hradil, and F. Svec, J. Chromatogr. 552, 365 (1991).

    Article  CAS  Google Scholar 

  18. A. V. Kiselev, Intermolecular Interactions in Adsorption and Chromatography (Vysshaya Shkola, Moscow, 1986) [in Russian].

    Google Scholar 

  19. E. Glueckauf, J. Chem. Soc., 1302 (1947).

  20. E. Glueckauf, J. Chem. Soc. Trans. Faraday 60, 729 (1964).

    CAS  Google Scholar 

  21. A. I. M. Keulemans, Gas Chromatography, Ed. by C. G. Verver (Reinhold, New York, 1957; Inostrannaya Literature, Moscow, 1959).

    Google Scholar 

  22. J. F. K. Huber and R. G. Gerritse, J. Chromatogr. 58, 134 (1971).

    Google Scholar 

  23. N. A. Chuduk, Yu. A. Eltekov, and A. V. Kiselev, J. Colloid Interface Sci. 84, 149 (1981).

    Article  CAS  Google Scholar 

  24. J.-M. Lehn, Supramolecular Chemistry (VCH, Weinheim, 1995).

    Google Scholar 

  25. N. A. El’tekova and Yu. A. El’tekov, Zh. Fiz. Khim. 74, 1468 (2000) [Russ. J. Phys. Chem. 74, 1324 (2000)].

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    N. A. El’tekova & Yu. A. El’tekov

Authors
  1. N. A. El’tekova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. A. El’tekov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © N.A. El’tekova, Yu.A. El’tekov, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 2, pp. 308–314.

Rights and permissions

Reprints and permissions

About this article

Cite this article

El’tekova, N.A., El’tekov, Y.A. Isotherms of adsorption of aromatic compounds on cellulose from heptane-isopropanol solutions. Russ. J. Phys. Chem. 80, 243–248 (2006). https://doi.org/10.1134/S0036024406020221

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024406020221

Keywords

Search

Navigation