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Dissociation constants for the zinc(II)-8-hydroxyquinoline complexes in aqueous and sodium dodecyl sulfate micellar solutions

Russian Journal of Physical Chemistry volume 80, pages 90–94 (2006)Cite this article

Abstract

The constants of dissociation of 8-hydroxyquinoline (pK 1 and pK 2) and of its complexation with zinc ions (logβ1, logβ2) in sodium nitrate aqueous solutions at 293 K were calculated by modeling potentiometric titration data. The values of logβ were obtained under conditions such that the complexes occurred simultaneously in the solution and at optimum values of the ionic strength and the ratio between the metal and ligand concentrations. The apparent constants of dissociation of 8-hydroxyquinoline and of its complexation with zinc ions in a 0.01 M sodium dodecyl sulfate solution were calculated. An increase in pK and logβ was explained by the stabilization of the different forms of the ligand and its complexes in the surfactant micellar phase.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya 1, Ivanovo, 153045, Russia

    L. M. Ramenskaya & O. V. Kraeva

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  1. L. M. Ramenskaya
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  2. O. V. Kraeva
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Original Russian Text © L. M. Ramenskaya, O. V. Kraeva, 2006, published in Zhurnal Fizicheskoi Khimii, 2006, Vol. 80, No. 1, pp. 100–105.

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Ramenskaya, L.M., Kraeva, O.V. Dissociation constants for the zinc(II)-8-hydroxyquinoline complexes in aqueous and sodium dodecyl sulfate micellar solutions. Russ. J. Phys. Chem. 80, 90–94 (2006). https://doi.org/10.1134/S0036024406010146

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  • DOI: https://doi.org/10.1134/S0036024406010146

Keywords

  • Surfactant
  • Ionic Strength
  • Sodium Dodecyl Sulfate
  • Dissociation Constant
  • Potentiometric Titration