Abstract—The paper analyzes the phases crystallizing in the Ca,Ba||F,Cl, ternary reciprocal system and describes ion-exchange and complexation reactions therein. The system is partitioned into simplexes using graph theory. A phase tree of the system has been designed, on the basis of which the number and compositions of phases crystallizing in stable elements have been predicted. A 3D model of the phase assemblage of the Ca,Ba||F,Cl system has been designed in the KOMPAS 3D v21 software. The presence of a quasi-binary eutectic and the stability of the crystallizing phases (CaF2 and BaCl2) on the CaF2–BaCl2 stable diagonal were confirmed by thermogravimetry (TG) and X-ray powder diffraction (XRD).
Similar content being viewed by others
REFERENCES
D. Sveinbjörnsson, A. S. Christiansen, R. Viskinde, et al., J. Electrochem. Soc. 161, A1432 (2014). https://doi.org/10.1149/2.1061409jes
R. Semwal, C. Ravi, R. Kumar, et al., Org. Chem. 84, 792 (2019). https://doi.org/10.1021/acs.joc.8b02637
Q. Gong, W. Ding, A. Bonk, et al., J. Power Sources 475, 228674 (2020). https://doi.org/10.1016/j.jpowsour.2020.228674
S. S. Abdullaeva, F. M. Mammadov, and I. B. Bakhtiyarly, Russ. J. Inorg. Chem. 65, 100 (2020). https://doi.org/10.1134/S0036023619110020
U. A. Gasanova, O. M. Aliev, I. B. Bakhtiyarly, et al., Russ. J. Inorg. Chem. 64, 242 (2019). https://doi.org/10.1134/S0036023619020074
S. K. Jahangirova, S. H. Mammadov, D. S. Ajdarova, et al., Russ. J. Inorg. Chem. 64, 1169 (2019). https://doi.org/10.1134/S0036023619090092
I. Nizomov and L. Soliev, Russ. J. Inorg. Chem. 64, 531 (2019). https://doi.org/10.1134/S0036023619030148
B. D. Babaev, High Temperature 52, 736 (2014). https://doi.org/10.1134/S0018151X14050010
I. Rychlowska–Himmel and M. Bosacka, Thermochim. Acta 503–504, 1325 (2010). https://doi.org/10.1016/j.tca.2010.03.002
P. Haseli, R. Jacob, and M. Liu, Thermochim. Acta 695, 178811 (2021). https://doi.org/10.1016/j.tca.2020.178811
N. A. Kozyreva and E. S. Gryzlova, Russ. J. Inorg. Chem. 54, 772 (2009).
O. S. Kudryashova, A. M. Elokhov, E. E. Garbuz, et al., Russ. J. Inorg. Chem. 65, 1905 (2020). https://doi.org/10.1134/S0036023620120104
V. I. Posypaiko and E. A. Alekseeva, Fusibility Diagrams for Salt Systems, part III (Metallurgiya, Moscow, 1979) [in Russian].
D. A. Wenz, I. Johnson, and R. D. Wolson, J. Chem. Eng. Data 14, 250 (1969). https://doi.org/10.1021/je60041a027
N. K. Voskresenskaya, N. N. Evseeva, S. I. Berul’, et al., Handbook of Fusibility of Anhydrous Inorganic Salt Systems, vol. 2 (Izd. AN SSSR, Moscow, 1961) [in Russian].
G. A. Bukhalova and A. G. Bergman, Zh. Obshch. Khim. 21, 1570 (1951).
P. P. Fedorov, I. I. Buchinskaya, N. A. Ivanovskaya, et al., Dokl. AN 401, 652 (2005).
A. Düvel, P. Heitjans, P. P. Fedorov, et al., Solid State Sci. 83, 188 (2018). https://doi.org/10.1016/j.solidstatesciences.2018.05.011
O. Ore, Graph Theory (Nauka, Moscow, 1980) [in Russian].
N. B. Ganin, Design and Strength Calculations in the System KOMIIAC-3D V13 (DMK Press, Moscow, 2011) [in Russian].
OOO “ASKON—Design systems.” https://kompas.ru/ (dated October 27, 2022).
A. V. Burchakov, I. K. Garkushin, I. M. Kondratyuk, et al., Russ. J. Inorg. Chem. 66, 1021 (2021). https://doi.org/10.1134/S0036023621070044
V. P. Egunov, Introduction to Thermal Analysis (Samara, 1996) [in Russian].
M. Wagner, Thermal Analysis in Practice: Fundamental Aspects (Hanser Publications, 2018).
Yu. V. Moshchenskii, Prib. Tekh. Eksper. 46, 143 (2003).
S. V. Fedotov and Yu. V. Moshchenskii, Interface Software DSCTool (Samar. Gos. Tekhn. Univ., Samara, 2004) [in Russian].
Thermal Constants of Substances: A Handbook, Ed. by V. P. Glushko (VINITI, Moscow, 1981) [in Russian].
Funding
The work was supported by the Ministry of Science and Higher Education of the Russian Federation (theme No. FSSE-2023-0003) as part of the Government assignment to Samara State Technical University.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Fedorova
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Rights and permissions
About this article
Cite this article
Slavnov, T.D., Egorova, E.M., Garkushin, I.K. et al. Phase Tree, Analysis of Crystallizing Phases, and Description of Chemical Interaction in the Ca,Ba||F,Cl Three-Component Reciprocal System. Russ. J. Inorg. Chem. (2024). https://doi.org/10.1134/S0036023623602556
Received:
Revised:
Accepted:
Published:
DOI: https://doi.org/10.1134/S0036023623602556