Abstract
A new method was proposed to synthesize aerogels based on Al2O3–TiO2 by the hydrolysis of mixed solutions of titanium tetrachloride and aluminum nitrate in the presence of propylene oxide, followed by supercritical drying of the obtained gels. The aerogels are characterized by a high specific surface area (140–500 m2/g) and a high specific porosity (1.7–2.7 cm3/g). Heat treatment of the Al2O3–TiO2 aerogels at temperatures up to 600°C does not lead to crystallization of titanium dioxide, whereas the formation of crystalline anatase in aerogels based on individual TiO2 is observed already at a temperature of 450°C. Using the standardized ISO 24443-2016 method, the SPF value of the obtained materials was determined, which turned out to be comparable to the characteristics of a commercial inorganic UV filter based on TiO2 (Kronos 1171). At the same time, the photocatalytic activity of the Al2O3–TiO2 aerogels turned out to be more than 120 times lower than the similar characteristics of the commercial UV filter based on titanium dioxide. The results obtained demonstrated that the Al2O3–TiO2 aerogels are promising as components of sunscreens.
Similar content being viewed by others
REFERENCES
S.-G. Jin, F. Padron, and G. P. Pfeifer, ACS Omega 7, 32936 (2022). https://doi.org/10.1021/acsomega.2c04424
K. C. Guerra, N. Zafar, and J. S. Crane, Skin Cancer Prevention (Treasure Island, StatPearls Publishing, 2023). https://pubmed.ncbi.nlm.nih.gov/30137812/.
G. J. Nohynek and H. Schaefer, Regul. Toxicol. Pharmacol. 33, 285 (2001). https://doi.org/10.1006/rtph.2001.1476
H. Gonzalez, N. Tarras-Wahlberg, B. Stromdahl, et al., BMC Dermatol. 7, 1 (2007). https://doi.org/10.1186/1471-5945-7-1
B. Gabard Sunscreens, Cosmetics (Springer, Berlin, 1999). https://doi.org/10.1007/978-3-642-59869-2_9
A. M. Bryden, H. Moseley, S. H. Ibbotson, et al., Br. J. Dermatol. 155, 737 (2006). https://doi.org/10.1111/j.1365-2133.2006.07458.x
F. C. Victor, D. E. Cohen, and N. A. Soter, J. Am. Acad. Dermatol. 62, 605 (2010). https://doi.org/10.1016/j.jaad.2009.06.084
S. L. Schneider and H. W. Lim, Photodermatol. Photoimmunol. Photomed. 35, 442 (2019). https://doi.org/10.1111/phpp.12439
N. Serpone, D. Dondi, and A. Albini, Inorg. Chim. Acta 360, 794 (2007). https://doi.org/10.1016/j.ica.2005.12.057
M. Morsella, N. D' Alessandro, A. E. Lanterna, et al., ACS Omega 1, 464 (2016). https://doi.org/10.1021/acsomega.6b00177
K. Nakata and A. Fujishima, J. Photochem. Photobiol. C Photochem. Rev. 13, 169 (2012). https://doi.org/10.1016/j.jphotochemrev.2012.06.001
M. Horie, S. Sugino, H. Kato, et al., Toxicol. Mech. Methods 26, 284 (2016). https://doi.org/10.1080/15376516.2016.1175530
S. Sun, P. Song, J. Cui, et al., Catal. Sci. Technol. 9, 4198 (2019). https://doi.org/10.1039/C9CY01020C
E. Jang, K. Sridharan, Y. M. Park, et al., Chem. A Eur. J. 22, 12022 (2016). https://doi.org/10.1002/chem.201600815
L. C. Becker, I. Boyer, W. F. Bergfeld, et al., Int. J. Toxicol. 35, 16 (2016). https://doi.org/10.1177/1091581816677948
G. Cassin, S. Diridollou, F. Flament, et al., Int. J. Cosmet. Sci. 40, 58 (2018). https://doi.org/10.1111/ics.12433
K. E. Yorov, I. V. Kolesnik, I. P. Romanova, et al., J. Supercrit. Fluids 169, 105099 (2021). https://doi.org/10.1016/j.supflu.2020.105099
A. C. Pierre and G. M. Pajonk, Chem. Rev. 102, 4243 (2002). https://doi.org/10.1021/cr0101306
N. Hüsing and U. Schubert, Angew. Chem. Int. Ed. 37, 22 (1998). https://doi.org/10.1002/(SICI)1521-3773(19980202)3-7:1/2<22::AID-ANIE22>3.0.CO;2-I
A. Feinle, M. S. Elsaesser, and N. Hüsing, Chem. Soc. Rev. 45, 3377 (2016). https://doi.org/10.1039/C5CS00710K
K. E. Yorov, A. E. Baranchikov, M. A. Kiskin, et al., Russ. J. Coord. Chem. 48, 89 (2022). https://doi.org/10.1134/S1070328422020014
P. Singh and A. Nanda, Int. J. Cosmet. Sci. 36, 273 (2014). https://doi.org/10.1111/ics.12124
L. Chen, J. Zhu, Y.-M. Liu, et al., J. Mol. Catal. A Chem. 255, 260 (2006). https://doi.org/10.1016/j.molcata.2006.04.043
R. Moussaoui, K. Elghniji, M. ben Mosbah, et al., J. Saudi Chem. Soc. 21, 751 (2017). https://doi.org/10.1016/j.jscs.2017.04.001
J. Donėlienė, E. Fataraitė-Urbonienė, N. Danchova, et al., Gels 8, 422 (2022). https://doi.org/10.3390/gels8070422
B. Gawel, K. Gawel, and G. Øye, Materials 3, 2815 (2010). .https://doi.org/10.3390/ma3042815
S. A. Lermontov, E. A. Straumal, A. A. Mazilkin, et al., Mater. Lett. 215, 19 (2017). https://doi.org/10.1016/j.matlet.2017.12.031
K. E. Yorov, N. A. Sipyagina, A. N. Malkova, et al., Inorg. Mater. 52, 163 (2016). https://doi.org/10.1134/S0020168516020035
K. E. Yorov, N. A. Sipyagina, A. E. Baranchikov, et al., Russ. J. Inorg. Chem. 61, 1339 (2016). https://doi.org/10.1134/S0036023616110048
A. E. Baranchikov, G. P. Kopitsa, K. E. Yorov, et al., Russ. J. Inorg. Chem. 66, 874 (2021). https://doi.org/10.1134/S003602362106005X
J. Livage, M. Henry, and C. Sanchez, Prog. Solid State Chem. 18, 259 (1988). https://doi.org/10.1016/0079-6786(88)90005-2
A. E. Gash, T. M. Tillotson, Jr., J. H. Satcher, et al., J. Non. Cryst. Solids 285, 22 (2001). https://doi.org/10.1016/S0022-3093(01)00427-6
H. Itoh, T. Tabata, M. Kokitsu, et al., J. Ceram. Soc. Jpn. 101 (1177), 1081 (1993). https://doi.org/10.2109/jcersj.101.1081
T.-Y. Wei, C.-H. Chen, K.-H. Chang, et al., Chem. Mater. 21, 3228 (2009). https://doi.org/10.1021/cm9007365
T. F. Baumann, A. E. Gash, S. C. Chinn, et al., Chem. Mater. 17, 395 (2005). https://doi.org/10.1021/cm048800m
S. A. Lermontov, A. N. Malkova, N. A. Sipyagina, et al., J. Sol-Gel Sci. Technol. 84, 377 (2017). https://doi.org/10.1007/s10971-017-4429-5
S. A. Lermontov, L. L. Yurkova, E. A. Straumal, et al., Russ. J. Inorg. Chem. 63, 303 (2018). https://doi.org/10.1134/S0036023618030142
K. E. Yorov, A. D. Yapryntsev, A. E. Baranchikov, et al., J. Sol-Gel Sci. Technol. 86, 400 (2018). https://doi.org/10.1007/s10971-018-4647-5
S. V. Kameneva, K. E. Yorov, R. K. Kamilov, et al., J. Sol-Gel Sci. Technol. 107, 586 (2023). https://doi.org/10.1007/s10971-023-06149-z
J. Rouquerol, P. Llewellyn, and F. Rouquerol, Stud. Surf. Sci. Catal. 160, 49 (2007). https://doi.org/10.1016/S0167-2991(07)80008-5
Yu. Ya. Fialkov, Solvent as a Means of Controlling a Chemical Process (Khimiya, Moscow, 1990) [in Russian].
E. N. Kuzin and N. E. Krutchinina, Inorg. Mater. 55, 834 (2019). https://doi.org/10.1134/S0020168519080065
T.-H. Wang, A. M. Navarrete-López, S. Li, et al., J. Phys. Chem. A 114, 7561 (2010). https://doi.org/10.1021/jp102020h
J. Archambault and R. Rivest, Can. J. Chem. 36, 1461 (1958). https://doi.org/10.1139/v58-216
T. Cottineau, M. Richard-Plouet, A. Rouet, et al., Chem. Mater. 20, 1421 (2008). https://doi.org/10.1021/cm702531q
H.-H. Emons, E. Janneck, and K. Pollmer, Z. Anorg. Allg. Chem. 511, 135 (1984). https://doi.org/10.1002/zaac.19845110415
H. Suzuki and S.-I. Ishiguro, Acta Crystallogr. Sect. C 54, 586 (1998). https://doi.org/10.1107/S0108270197018817
Titanium(IV), Zirconium, Hafnium and Thorium, in Hydrolysis of Metal Ions, Ed. by P. L. Brown and C. Ekberg (Wiley, Weinheim, 2016). https://doi.org/10.1002/9783527656189.ch10
Aluminium, Gallium, Indium and Thallium, in Hydrolysis of Metal Ions, Ed. by P. L. Brown and C. Ekberg (Wiley, Weinheim, 2016). https://doi.org/10.1002/9783527656189.ch13
A. E. Gash, T. M. Tillotson, J. H. Satcher, et al., Chem. Mater. 13, 999 (2001). https://doi.org/10.1021/cm0007611
X. Du, Y. Wang, X. Su, et al., Powder Technol. 192, 40 (2009). https://doi.org/10.1016/j.powtec.2008.11.008
M. Thommes, K. Kaneko, A. V. Neimark, et al., Pure Appl. Chem. 87, 1051 (2015). https://doi.org/10.1515/pac-2014-1117
M. Gao, B. Liu, P. Zhao, et al., J. Sol-Gel Sci. Technol. 91, 514 (2019). https://doi.org/10.1007/s10971-019-05057-5
A. Guinier and G. Fournet, Small-Angle X-ray Scattering (John Wiley & Sons Inc., New York, 1955). https://doi.org/10.1002/pol.1956.120199326
J. Teixeira, in On Growth and Form (Springer, Dordrecht, 1986). https://doi.org/10.1007/978-94-009-5165-5_9
D. Kim, J. Jung, and J. Ihm, Nanomaterials 8, 375 (2018). https://doi.org/10.3390/nano8060375
S. Keysar, Y. De Hazan, Y. Cohen, et al., J. Mater. Res. 12, 430 (1997). https://doi.org/10.1557/JMR.1997.0063
F. Meng, J. R. Schlup, and L. T. Fan, Chem. Mater. 9, 2459 (1997). https://doi.org/10.1021/cm9700662
J.-Y. Chane-Ching and L. C. Klein, J. Am. Ceram. Soc. 71, 86 (1988). https://doi.org/10.1111/j.1151-2916.1988.tb05765.x
M. Catauro and E. Tranquillo, G. Dal Poggetto, et al., Materials 11, 2367 (2018). https://doi.org/10.3390/ma11122364
M. Diko, Acta Geodyn. Geomater. 149 (2015). https://doi.org/10.13168/AGG.2015.0052
G. Feng, F. Jiang, W. Jiang, et al., Ceram. Int. 45, 18704 (2019). https://doi.org/10.1016/j.ceramint.2019.06.096
S. A. Kirillova, V. I. Almjashev, and V. V. Gusarov, Russ. J. Inorg. Chem. 56, 1464 (2011). https://doi.org/10.1134/S0036023611090117
G. P. Dransfield, Radiat. Prot. Dosimetry 91, 271 (2000). https://doi.org/10.1093/oxfordjournals.rpd.a033216
M. G. Kim, J. M. Kang, J. E. Lee, et al., ACS Omega 6, 10668 (2021). https://doi.org/10.1021/acsomega.1c00043
H. Nishizawa and Y. Aoki, J. Solid State Chem. 56, 158 (1985). https://doi.org/10.1016/0022-4596(85)90052-0
A. K. Bachina, O. V. Almjasheva, V. I. Popkov, et al., J. Cryst. Growth 576, 126371 (2021). https://doi.org/10.1016/j.jcrysgro.2021.126371
O. V. Almjasheva, N. A. Lomanova, V. I. Popkov, et al., Nanosyst. Physics, Chem. Mat. 10, 428 (2019). https://doi.org/10.17586/2220-8054-2019-10-4-428-437
H. Lin, L. Li, M. Zhao, et al., J. Am. Chem. Soc. 134, 8328 (2012). https://doi.org/10.1021/ja3014049
B. Hammouda, J. Appl. Crystallogr. 43, 716 (2010). https://doi.org/10.1107/S0021889810015773
P. W. Schmidt, D. Avnir, D. Levy, et al., J. Chem. Phys. 94, 1474 (1991). https://doi.org/10.1063/1.460006
V. Pogorelov, I. Doroshenko, G. Pitsevich, et al., J. Mol. Liq. 235, 7 (2017). https://doi.org/10.1016/j.molliq.2016.12.037
J. M. Roscoe and J. P. D. Abbatt, J. Phys. Chem. A 109, 9028 (2005). https://doi.org/10.1021/jp050766r
K. Thomas, P. E. Hoggan, L. Mariey, et al., Catal. Lett. 46, 77 (1997). https://doi.org/10.1023/A:1019017123596
D. A. H. Hanaor and C. C. Sorrell, J. Mater. Sci. 46, 855 (2011). https://doi.org/10.1007/s10853-010-5113-0
ArierU. O. Akkaya and F. Z. Tepehan, Composites Part B 58, 147 (2014). https://doi.org/10.1016/j.compositesb.2013.10.023
F. Hanini, A. Bouabellou, Y. Bouachiba, et al., IOSR J. Eng. 3, 21 (2013). https://doi.org/10.9790/3021-031112128
S. Riaz, Sajid-ur-Rehman, M. Abutalib, et al., J. Electron. Mater. 45, 5185 (2016). https://doi.org/10.1007/s11664-016-4754-4
E. O. Filatova and A. S. Konashuk, J. Phys. Chem. C 119, 20755 (2015). https://doi.org/10.1021/acs.jpcc.5b06843
M. P. Prange, X. Zhang, E. S. Ilton, et al., J. Chem. Phys. 149, 024502 (2018). https://doi.org/10.1063/1.5037104
F. Tzompantzi, Y. Piña, A. Mantilla, et al., Catal. Today 220–222, 49 (2014). https://doi.org/10.1016/j.cattod.2013.10.027
O. Carp, C. L. Huisman, and A. Reller, Prog. Solid State Chem. 32, 33 (2004).https://doi.org/10.1016/j.progsolidstchem.2004.08.001
ACKNOWLEDGMENTS
This work was carried out using equipment of the Center for Shared Use of Physical Methods of Investigation of Substances and Materials, Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia. The XRD measurements were performed using the equipment of the Shared Research Center FSRC “Crystallography and Photonics” RAS supported by the Ministry of Science and Higher Education of the Russian Federation.
Funding
This work was supported by the Russian Science Foundation (grant no. 22-13-00410).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by V. Glyanchenko
Publisher’s Note.
Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Polevoi, L.A., Kolesnik, I.V., Kopitsa, G.P. et al. Epoxide-Mediated Synthesis of Two-Component Al2O3–TiO2 Aerogels and Their UV-Protective Characteristics. Russ. J. Inorg. Chem. 68, 1848–1864 (2023). https://doi.org/10.1134/S0036023623602209
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023623602209