Abstract
Cesium sulfatoscandate CsSc(SO4)2 (space group P\(\bar {3}\), a = b = 5.0971(1) Å, c = 8.6924(5) Å, V = 195.580(2) Å3, Z = 1) has been crystallized from aqueous solutions in layered hexagonal prisms sized up to 50 µm and up to 2–5 µm thick. Its water solubility is 0.0104 mol/L at 25 ± 1°С. A way to reduce the solubility of scandium as CsSc(SO4)2 is to increase acidity to 3.5–5.5 М H2SO4 and add Cs2SO4. Experimental evidence is supported by calculations that took into account changes in the ionic strength of the solution and the influence of the simultaneous presence of Cs+ and \({\text{HSO}}_{4}^{ - }\) ions. The results will be useful for those who will study the behavior of rare-metal compounds having similar properties and their separation.
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REFERENCES
E. P. Lokshin and O. A. Tareeva, Development of Technology for Extracting Rare Earth Elements during Sulfuric acid Processing of Khibiny Apatite Concentrate for Mineral Fertilizers (KNTs RAN, Apatity, 2015) [in Russian].
F. Sadri, A. M. Nazari, and A. Ghahreman, J. Rare Earths 35, 739 (2017). https://doi.org/10.1016/S1002-0721(17)60971-2
E. P. Lokshin and O. A. Tareeva, Russ. J. Appl. Chem. 83, 951 (2010). https://doi.org/10.1134/S1070427210060042
E. P. Lokshin, O. A. Tareeva, K. G. Ivlev, and T. G. Kashulina, Rus. J. Appl. Chem. 78, 1058 (2005). https://doi.org/10.1007/s11167-005-0449-y
V. I. Pet’kov, A. I. Bokov, E. A. Asabina, and E. Yu. Borovikova, Russ. J. Gen. Chem. 92, 2334 (2022). https://doi.org/10.1134/S1070363222110172
N. N. Bushuev, G. S. Tyul’bendzhyan, Y. A. Velikodnyi, et al., Russ. J. Inorg. Chem. 66, 405 (2021). https://doi.org/10.1134/S0036023621030049
N. N. Bushuev, A. N. Egorova, and G. S. Tyul’-bendzhyan, Inorg. Mater. 57, 142 (2021). https://doi.org/10.1134/S0020168521020047
A. G. Suss, A. B. Kozyrev, and A. V. Panov, Patent RF 2647398, 2018.
L. A. Pasechnik, V. M. Skachkov, A. Yu. Chufarov, et al., Hydrometallurgy 202, 105597 (2021). https://doi.org/10.1016/j.hydromet.2021.105597
V. P. Volkov, A. P. Gushchin, and B. A. Soloviev, Patent RF 2079431, 1997.
L. N. Komissarova, G. Ya. Pushkina, and V. M. Shanskii, Rare Earth Compounds: Sulfates, Selenates, Tellurates, and Chromates (Nauka, Moscow, 1986) [in Russian].
L. N. Komissarova, Inorganic and Analytical Chemistry of Scandium (Editorial URSS, Moscow, 2001) [in Russian].
L. A. Pasechnik, A. P. Tyutyunnik, A. N. Enyashin, et al., J. Solid State Chem. 255, 50 (2017). https://doi.org/10.1016/j.jssc.2017.07.037
L. A. Pasechnik, A. P. Tyutyunnik, A. N. Enyashin, et al., CrystEngComm 20, 3772 (2018). https://doi.org/10.1039/C8CE00593A
A. Porvali, B. P. Wilson, and M. Lundstrom, Waste Manage. 71, 381 (2018). https://doi.org/10.1016/j.wasman.2017.10.031
L. A. Pasechnik, N. A. Sabirzyanov, and S. P. Yatsenko, Omsk Sci. Bull. 25, 219 (2003). www.omgtu.ru/general_information/media_omgtu/ journal_of_omsk_research_journal/files/arhiv/2003/ 4(25)%20pdf.pdf.
G. S. Skiba, V. Y. Kuznetsov, M. P. Rys’kina, and G. V. Ponomarenko, Russ. J. Inorg. Chem. 64, 1172 (2019). https://doi.org/10.1134/S0036023619090201
A. Balinski, P. Atanasova, O. Wiche, et al., Hydrometallurgy 186, 176 (2019). https://doi.org/10.1016/j.hydromet.2020.105345
N. B. Voskoboinikov and S. G. Skiba, New Methods for Studying Solubility in Water–Salt Systems (Nauka, Leningrad, 1986) [in Russian].
L. N. Komissarova, B. I. Bashkov, V. M. Shatskii, and L. N. Komissarova, Zh. Neorg. Khim. 15, 1507 (1970).
K. N. Han, Mining. Metall. Explor. 36, 215 (2019). https://doi.org/10.1007/s42461-018-0029-3
L. G Ivanov-Emin, V. G. Korotaeva, A. I. Remizov, and B. N. Ezhov, Zh. Neorg. Khim. 11, 511 (1966).
R. A. Robinson and R. H. Stokes, Electrolyte Solutions, 2nd Ed. (Butterworths, London, 1968).
Yu. V. Shvarov, Appl. Geochem. 55, 17 (2015). https://doi.org/10.1016/j.apgeochem.2014.11.021
M. E. Tarnopolskaia, A. Y. Bychkov, and Y. V. Shvarov, Geochem. Int. 54, 640 (2016). https://doi.org/10.1134/S0016702916070107
G. Das, M. M. Lencka, A. Eslamimanesh, et al., J. Chem. Thermodyn. 131, 499 (2019). https://doi.org/10.1016/j.jct.2018.10.020
K. N. Han and R. Kim, Minerals 11, 670 (2021). https://doi.org/10.3390/min11070670
W. D. Judge, K. L. Ng, G. A. Moldoveanu, et al., Hydrometallurgy 218 (2023). https://doi.org/10.1016/j.hydromet.2023.106054
E. P. Lokshin and O. A. Tareeva, Russ. J. Inorg. Chem. 52, 1830 (2007). https://doi.org/10.1134/S0036023607120042
A. M. Elokhov, O. S. Kudryashova, L. M. Lukmanova, et al., Russ. J. Inorg. Chem. 67, 2023 (2022). https://doi.org/10.1134/S003602362260099X
ACKNOWLEDGMENTS
The X-ray powder diffraction experiments were carried out in the “X-ray Structural Analysis” Shared Facilities Center of the Institute of Solid-State Chemistry, Ural Branch of the Russian Academy of Sciences.
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This work was fulfilled as part of the Government assignment to the Institute of Solid-State Chemistry, Ural Branch of the Russian Academy of Sciences.
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Pasechnik, L.A., Medyankina, I.S., Tyutyunnik, A.P. et al. Solubility of Scandium Cesium Double Sulfate CsSc(SO4)2 in Sulfuric Acid Solutions. Russ. J. Inorg. Chem. 68, 1818–1823 (2023). https://doi.org/10.1134/S0036023623602088
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DOI: https://doi.org/10.1134/S0036023623602088