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Chemical Deposition of CdxPb1 – xS/CdyS Thin-Film Composite Structures

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Thin films of CdxPb1 – xS (0 ≤ x ≤ 0.094) substitutional solid solutions of cubic structure B1 (space group Fm\(\overline 3 m\)) were prepared by chemical deposition and characterized by X-ray diffraction, scanning electron microscopy, EDX elemental analysis, and Raman spectroscopy. Once the cadmium sulfate concentration in the batch reached some critical value (0.1 mol/L), the films formed involved two autonomous phases: CdxPb1 – xS substitutional solid solutions and hexagonal cadmium sulfide CdyS of structure В4 (space group P63mc). The method and its parameters as proposed are efficient for manufacturing heterostructures in the CdS–PbS system in one-pot deposition.

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ACKNOWLEDGMENTS

The authors appreciate the help of E.G. Vovkotrub, the senior researcher of the Institute of High-Temperature Electrochemistry, Ural Branch of the Russian Academy of Sciences, in Raman spectroscopy.

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Authors and Affiliations

  1. Ural Federal University Named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia

    A. D. Selyanina, L. N. Maskaeva & V. F. Markov

  2. Ural Institute of State Fire Service, the EMERCOM of Russia, 620062, Yekaterinburg, Russia

    L. N. Maskaeva & V. F. Markov

  3. Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, 620108, Yekaterinburg, Russia

    V. I. Voronin

  4. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    I. A. Anokhina

Authors
  1. A. D. Selyanina
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  2. L. N. Maskaeva
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  3. V. I. Voronin
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  4. I. A. Anokhina
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Correspondence to A. D. Selyanina.

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Translated by O. Fedorova

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Selyanina, A.D., Maskaeva, L.N., Voronin, V.I. et al. Chemical Deposition of CdxPb1 – xS/CdyS Thin-Film Composite Structures. Russ. J. Inorg. Chem. 68, 22–29 (2023). https://doi.org/10.1134/S0036023622700115

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  • DOI: https://doi.org/10.1134/S0036023622700115

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