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Conversions in Silicon and Aluminum Alkoxide Gels during the Synthesis of Sialons as Probed by IR Spectroscopy

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

A comparison infrared spectroscopic study of reactions under nitrogen in various batch compositions for the preparation of β-sialon Si3Al3O3N5 from various crystalline nitrides (AlN and Si3N4) and amorphous oxides prepared by the sol–gel process from silicon and aluminum alkoxides, and from mixed aluminosilicate xerogels nitrided by molecular nitrogen at various steps of the β-sialon synthesis. The IR absorption bands at ~1080−1040 and 580 cm–1 indicate that the sialons prepared from different batch compositions are isostructural to β-Si3N4, thereby verifying the formation of β-sialon of the tailored composition Si3Al3O3N5.

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Funding

The work was supported by the Russian Foundation for Basic Research (project No. 20-03-00455a).

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Authors and Affiliations

  1. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991, Moscow, Russia

    S. N. Ivicheva, N. A. Ovsyannikov, A. S. Lysenkov & Yu. F. Kargin

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  1. S. N. Ivicheva
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  2. N. A. Ovsyannikov
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  3. A. S. Lysenkov
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  4. Yu. F. Kargin
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Correspondence to S. N. Ivicheva.

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Translated by O. Fedorova

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Ivicheva, S.N., Ovsyannikov, N.A., Lysenkov, A.S. et al. Conversions in Silicon and Aluminum Alkoxide Gels during the Synthesis of Sialons as Probed by IR Spectroscopy. Russ. J. Inorg. Chem. 67, 1908–1918 (2022). https://doi.org/10.1134/S0036023622601489

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