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Preparation and Characterization of Graphene Oxide Films with Metal Salts

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Film samples produced by codeposition of salts Na(form), Ni(form)2, Co(Аcac)3, and Pb(Аc)2 from graphene oxide dispersions are studied. The thus-prepared materials are characterized by spectral and X-ray analytical methods. The structure of graphene oxide containing salt crystals is studied by scanning electron microscopy (SEM). Crystallization occurs both on the surface and in the interlayer spaces of graphene oxide. No side processes occur during crystallization; the precursor salts retain their phase composition, except for lead acetate, which is partially hydrolyzed in aqueous solution. The incorporation of salt crystals increases film imperfection and enhances the resistivity of the material severalfold. The results of this study can appear useful in the development of graphene oxide based membranes.

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REFERENCES

  1. I. V. Kozerozhets, G. P. Panasyuk, E. A. Semenov, et al., Ceram. Int. 48, 7522 (2022). https://doi.org/10.1016/j.ceramint.2021.11.296

    Article  CAS  Google Scholar 

  2. I. V. Kozerozhets, G. P. Panasyuk, E. A. Semenov, et al., Ceram. Int. 46, 28961 (2020). https://doi.org/10.1016/j.ceramint.2020.08.067

    Article  CAS  Google Scholar 

  3. G. P. Panasyuk, I. V. Kozerozhets, E. A. Semenov, et al., Inorg. Mater. 55, 920 (2019). https://doi.org/10.1134/S0020168519090127

    Article  Google Scholar 

  4. G. P. Panasyuk, L. A. Azarova, V. N. Belan, et al., Theor. Found. Chem. Eng. 52, 879 (2018). https://doi.org/10.1134/S0040579518050202

    Article  CAS  Google Scholar 

  5. A. A. Mikhaylov and A. G. Medvedev, Mason, et al., J. Mater. Chem. A 3, 20681 (2015). https://doi.org/10.1039/c5ta04514b

    Article  CAS  Google Scholar 

  6. Y. V. Ioni, S. V. Kraevsky, Y. A. Groshkova, et al., Mendeleev Commun. 31, 718 (2021). https://doi.org/10.1016/j.mencom.2021.09.042

    Article  CAS  Google Scholar 

  7. Z. Xu, S. Zhu, M. Wang, et al., ACS Appl. Mater. Interfaces 7, 1355 (2015). https://doi.org/10.1021/am507798d

    Article  CAS  PubMed  Google Scholar 

  8. Z. U. Khan, A. Kausar, H. Ullah, et al., J. Plast. Film Sheeting 32, 336 (2016). https://doi.org/10.1177/8756087915614612

    Article  CAS  Google Scholar 

  9. O. Mrózek, L. Melounková, D. Smržová, et al., J. Hazard. Mater. 398, 123114 (2020). https://doi.org/10.1016/j.jhazmat.2020.123114

    Article  CAS  PubMed  Google Scholar 

  10. S. Shahriari, M. Sastry, S. Panjikar, et al., Nanotechnol. Sci. Appl. 14, 197 (2021). https://doi.org/10.2147/NSA.S334487

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  11. Matharu R. Kaur, T. A. Tabish, T. Trakoolwilaiwan, et al., J. Colloid Interface Sci. 571, 239 (2020). https://doi.org/10.1016/j.jcis.2020.03.037

    Article  CAS  PubMed  Google Scholar 

  12. Y. V. Ioni, S. E. Lyubimov, V. A. Davankov, et al., Russ. J. Inorg. Chem. 58, 392 (2013). https://doi.org/10.1134/s0036023613040062

    Article  CAS  Google Scholar 

  13. L. Fritea, F. Bănică, T. O. Costea, et al., J. Electroanal. Chem. 830–831, 63 (2018). https://doi.org/10.1016/j.jelechem.2018.10.015

    Article  CAS  Google Scholar 

  14. K. Z. Riahi, N. Sdiri, D. J. Ennigrou, et al., J. Mol. Struct. 1216, 128304 (2020). https://doi.org/10.1016/j.molstruc.2020.128304

    Article  CAS  Google Scholar 

  15. Y. V. Ioni, Y. A. Groshkova, S. P. Gubin, et al., Nanotechnol. Russ. 15, 163 (2020). https://doi.org/10.1134/S1995078020020111

    Article  CAS  Google Scholar 

  16. D. Dikin, S. Stankovich, E. Zimney, et al., Nature 448, 457 (2007). https://doi.org/10.1038/nature06016

    Article  CAS  PubMed  Google Scholar 

  17. Y. V. Ioni, Y. A. Groshkova, E. Y. Buslaeva, et al., Russ. J. Inorg. Chem. 66, 950 (2021). https://doi.org/10.1134/S0036023621060115

    Article  CAS  Google Scholar 

  18. D. I. Petukhov, O. O. Kapitanova, E. A. Eremina, et al., Mendeleev Commun. 31, 137 (2021). https://doi.org/10.1016/j.mencom.2021.03.001

    Article  CAS  Google Scholar 

  19. W. Cha-Umpong, E. Hosseini, A. Razmjou, et al., J. Membr. Sci. 598, 117687 (2019). https://doi.org/10.1016/j.memsci.2019.117687

    Article  CAS  Google Scholar 

  20. M. B. M. Y. Ang, M. R. Gallardo, G. V. C. Dizon, et al., J. Membr. Sci. 587, 117188 (2019). https://doi.org/10.1016/j.memsci.2019.117188

    Article  CAS  Google Scholar 

  21. L. Chen, G. Shi, J. Shen, et al., Nature 550, 380 (2017). https://doi.org/10.1038/nature24044

    Article  CAS  PubMed  Google Scholar 

  22. J.-C. Li, P.-X. Hou, and C. Liu, Small 13, 1702002 (2017). https://doi.org/10.1002/smll.201702002

    Article  CAS  Google Scholar 

  23. A. S. Kuzenkova, A. Y. Romanchuk, A. L. Trigub, et al., Carbon 158, 291 (2019). https://doi.org/10.1016/j.carbon.2019.10.003

    Article  CAS  Google Scholar 

  24. M. Wang, Y. Niu, J. Zhou, et al., Nanoscale 14587 (2016). https://doi.org/10.1039/c6nr03503e

  25. R. R. Amirov, J. Shayimova, Z. Nasirova, et al., Carbon 116, 356 (2017). https://doi.org/10.1016/j.carbon.2017.01.095

    Article  CAS  Google Scholar 

  26. A. Osman, S. Leaper, V. Sreepal, et al., Cryst. Growth Des. 19, 498 (2018). https://doi.org/10.1021/acs.cgd.8b01597

    Article  CAS  Google Scholar 

  27. I. V. Kozerozhets, G. P. Panasyuk, E. A. Semenov, et al., Inorg. Mater. 56, 716 (2020). https://doi.org/10.1134/S002016852007009

    Article  CAS  Google Scholar 

  28. G. P. Panasyuk, I. V. Kozerozhets, I. L. Voroshilov, et al., Russ. J. Phys. Chem. 89, 592 (2015). https://doi.org/10.1134/S0036024415040196

    Article  CAS  Google Scholar 

  29. G. P. Panasyuk, E. A. Semenov, I. V. Kozerozhets, et al., Dokl. Chem. 483, 272 (2018). https://doi.org/10.1134/S0012500818110022

    Article  CAS  Google Scholar 

  30. G. P. Panasyuk, V. N. Belan, I. L. Voroshilov, et al., Inorg. Mater. 46, 747 (2010). https://doi.org/10.1134/S0020168510070113

    Article  CAS  Google Scholar 

  31. I. V. Kozerozhets, G. P. Panasyuk, E. A. Semenov, et al., Russ. J. Inorg. Chem. 65, 1529 (2020). https://doi.org/10.1134/S0036023620100149

    Article  CAS  Google Scholar 

  32. I. M. Karzov, N. E. Sorokina, and V. V. Avdeev, Inorg. Mater. 45, 374 (2009). https://doi.org/10.1134/s0020168509040086

    Article  CAS  Google Scholar 

  33. M. I. Saidaminov, N. V. Maksimova, N. E. Sorokina, et al., Inorg. Mater. 49, 883 (2013). https://doi.org/10.1134/s0020168513090161

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

Facilities of the Shared Facilities Center of the Kurnakov Institute of General and Inorganic Chemistry, the Russian Academy of Sciences were used in the X-ray diffraction studies. For scanning electron microscopy experiments, facilities of the Educational and Methodological Center for Lithography and Microscopy at Moscow State University were used.

Funding

The study was supported by the Russian Science Foundation (project No. 22-19-00110).

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. V. Ioni, E. G. Rustamova & S. P. Gubin

  2. Lebedev Physical Institute, 119991, Moscow, Russia

    S. I. Chentsov

  3. Faculty of Physics, Moscow State University, 119991, Moscow, Russia

    I. V. Sapkov

  4. Graphenica, 107150, Moscow, Russia

    E. G. Rustamova

Authors
  1. Yu. V. Ioni
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  2. S. I. Chentsov
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  3. I. V. Sapkov
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  4. E. G. Rustamova
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  5. S. P. Gubin
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Corresponding author

Correspondence to Yu. V. Ioni.

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Translated by O. Fedorova

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Ioni, Y.V., Chentsov, S.I., Sapkov, I.V. et al. Preparation and Characterization of Graphene Oxide Films with Metal Salts. Russ. J. Inorg. Chem. 67, 1711–1717 (2022). https://doi.org/10.1134/S0036023622601076

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  • DOI: https://doi.org/10.1134/S0036023622601076

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