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Synthesis of Calcium Aluminosilicates from Nanostructured Synthetic Na Zeolites and Study of Their Sorption Properties

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Calcium aluminosilicates synthesized by chemical modification of nanostructured synthetic Na zeolites were characterized. The sorption properties were studied for calcium aluminosilicates with SiO2 : Al2O3 ratios of 2 : 1, 4 : 1, 6 : 1, 8 : 1, and 10 : 1. The maximum capacity of these compounds to sorb Cs+ ions under static conditions from solutions without salt background was shown to reach 1.45 mmol/g (192.7 mg/g). The results of this work allow one to consider these compounds as promising materials for the sorption and immobilization of long-lived radionuclides.

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ACKNOWLEDGMENTS

Atomic absorption analysis was made using equipment Far East Center of Structural Studies (Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, Vladivostok, Russia).

Funding

This work was performed under State assignment no. FWFN(0205)-2022-0002, topic 2, section 3 for the Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    P. S. Gordienko, S. B. Yarusova, I. A. Shabalin, A. B. Slobodyuk, E. A. Nekhlyudova, V. G. Kuryavyi, N. V. Polyakova & Yu. A. Parot’kina

  2. Vladivostok State University of Economics and Service, 690014, Vladivostok, Russia

    S. B. Yarusova & E. A. Nekhlyudova

  3. Far Eastern Federal University, 690922, Vladivostok, Russia

    O. O. Shichalin & E. K. Papynov

Authors
  1. P. S. Gordienko
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  2. S. B. Yarusova
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  3. I. A. Shabalin
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  4. A. B. Slobodyuk
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  5. E. A. Nekhlyudova
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  6. O. O. Shichalin
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  7. E. K. Papynov
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  8. V. G. Kuryavyi
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  9. N. V. Polyakova
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  10. Yu. A. Parot’kina
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Contributions

P.S. Gordienko and S.B. Yarusova conceived and designed the experiment. I.A. Shabalin and E.A. Nekhlyudova synthesized the samples. A.B. Slobodyuk made the NMR study of the samples. O.O. Shichalin and E.K. Papynov co-processed data and co-wrote the paper. V.G. Kuryavyi studied the morphological characteristics of the samples. N.V. Polyakova analyzed the elemental composition of the samples by energy-dispersive X-ray fluorescence spectroscopy. Yu.A. Parot’kina carried out atomic absorption spectrometry studies. All authors discussed the results.

Corresponding author

Correspondence to S. B. Yarusova.

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The authors declare that they have no conflicts of interest.

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Translated by V. Glyanchenko

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Gordienko, P.S., Yarusova, S.B., Shabalin, I.A. et al. Synthesis of Calcium Aluminosilicates from Nanostructured Synthetic Na Zeolites and Study of Their Sorption Properties. Russ. J. Inorg. Chem. 67, 1393–1399 (2022). https://doi.org/10.1134/S0036023622090042

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  • DOI: https://doi.org/10.1134/S0036023622090042

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