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Calcium Phosphate Apatites: Wet Formation, Thermal Transformations, Terminology, and Identification

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Apatite calcium phosphates have been synthesized at pH 9–11, Ca/P = 1.50–1.67 under variable isolation conditions. A complex procedure for identification of inclusion of amorphous calcium phosphate by precipitation of hydroxyapatite under non-equilibrium conditions, including XRD/FTIR/DTA methods. The maximal stabilization of amorphous phase inclusions in hydroxyapatite structure proceeds at precipitation pH 9, fast reaction of the chemicals without precipitate maturation stage under mother solution and careful dehydration by ethanol followed by heating at 400°C. Contradictions in reported physicochemical properties apatite calcium phosphates are related to formation of amorphous inclusions. A scheme of formation and thermal transformations of apatitic calcium phosphates under different equilibrium and formation conditions has been suggested for monophase stoichiometric hydroxyapatite, biphasic composites based on calcium-deficient hydroxyapatites, and amorphous calcium phosphate

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Funding

This work was financially supported by the State program of scientific research “Chemical Processes, Reagents, and Technologies, Bioregulators and Bioorganic Chemistry” under State Assignment 2.1.04.7 for 2021–2025 and the National Academy of Sciences of Belarus (project no. 2021-27-173 for 2021).

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, National Academy of Sciences of Belarus, 220072, Minsk, Belarus

    I. E. Glazov, V. K. Krut’ko, O. N. Musskaya & A. I. Kulak

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  1. I. E. Glazov
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  2. V. K. Krut’ko
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  3. O. N. Musskaya
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  4. A. I. Kulak
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Correspondence to I. E. Glazov.

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Translated by I. Kudryavtsev

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Glazov, I.E., Krut’ko, V.K., Musskaya, O.N. et al. Calcium Phosphate Apatites: Wet Formation, Thermal Transformations, Terminology, and Identification. Russ. J. Inorg. Chem. 67, 173–182 (2022). https://doi.org/10.1134/S0036023622020048

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