Abstract—
The complex formation and the ion-association of the ion-pair formed between the anionic chelate of molybdenum(VI)‒3,5-dinitrocatechol (3,5-DNC) with the cation of 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl-2H-tetrazolium bromide (MTT) in the liquid–liquid extraction system Mo(VI)‒3,5-DNC‒MTT‒H2O‒CHCl3 was studied by spectrophotometry. The optimum conditions for the chelate formation and extraction of the ion-associated complex Mo(VI)‒3,5-DNC‒MTT were established. The molar ratio of the components in the ion-associated complex Mo(VI)–3,5-DNC–MTT was determined by independent methods. The association process in aqueous phase and the extraction equilibria were investigated and quantitatively characterized. The following key constants of the processes were calculated: association constant, distribution constant, extraction constant and recovery factor. Based on this, a reaction scheme, a general formula and a structural formula of the complex were suggested.
Similar content being viewed by others
Change history
19 February 2020
erratum
REFERENCES
R. R. Moskalyk, Miner. Eng. 17, 393 (2004). https://doi.org/10.1016/j.mineng.2003.11.014
L. Cao L, J. Park, P. Fan, et al., NanoLett. 10, 1229 (2010). https://doi.org/10.1021/nl903727
K. W. Yu, H. N. Murthy, C. S. Jeong, et al., Process Biochem. 40, 2959 (2005). https://doi.org/10.1016/j.procbio.2005.01.015
D. M. LeMaster, M. Munnich, P. J. Parsons, et al., J. Inorg. Biochem. 100, 1410 (2006). https://doi.org/10.1016/j.jinorgbio.2006.03.014
F. A. Cotton, G. Wilkinson, C. A. Murillo et al., Advanced Inorganic Chemistry, 6th Ed. (Wiley, New Jersey, 1999).
V. V. Skopenko, A. Yu. Tsivadze, L. I. Sabranskiy, et al, Coordination Chemistry (Akademkniga, Moscow, 2007).
Yu. D. Tretyakov, L. I. Martinenko and A. N. Grigorev, Inorganic Chemistry (Moscow Univ., Moscow, 2007).
V. S. Sergienko, L. Kh. Minacheva and A. V. Churakov, Rus. J. Inorg. Chem. 55, 2001 (2010). https://doi.org/10.1134/S0036023610130012
W. Levason, G. Reid and W. Zhang, Coordin. Chem. Rev. 255, 1319 (2011). https://doi.org/10.1016/j.ccr.2010.11.019
M. F. Davis, W. Levason, G. Reid, et al., Dalt. Trans. 17, 2261 (2008). https://doi.org/10.1039/B716765B
I. I. Seifullina, N. V. Shmatkova and E. E. Martsinko, Russ. J. Coordin. Chem. 30, 214 (2010). https://doi.org/10.1023/B:RUCO.0000022120.49644.5c
F. Cheng, M. F. Davis, A. L. Hector, et al., Eur. J. Inorg. Chem. 2007, 2488 (2007). doiorg/https://doi.org/10.1002/ejic.200700233
G. S. Pokrovski, F. Martin, J. L. Hazemann, et al., Chem. Geol. 163, 151 (2000). https://doi.org/10.1016/S0009-2541(99)00102-3
D. Biller, C. Burschka, M. Penka, et al., Inorg. Chem. 41, 3901 (2002).https://doi.org/10.1021/ic0255757
A. T. Pilipenko and M. M. Tananayko, Mixed Ligands and Mixed Metal Complexes and Their Application in Analytical Chemistry (Khimiya, Moscow, 1983).
V. A. Nazarenko, Analytical Chemistry of Germanuim (Nauka, Moscow, 1973).
I. I. Seifullina, A. G. Pesaroglo, L. Kh. Minacheva, et al., Russ. J. Inorg. Chem. 51, 1892 (2006). https://doi.org/10.1134/S0036023606120096
L. Zaijun, P. Jiaomai and T. Jan, Anal. Chim. Acta 445, 153 (2001).https://doi.org/10.1016/S0003-2670(01)01259-4
F. N. Shi, L. C. Silva, M. J. Hardie, et al., Inorg. Chem. 46, 6502 (2007). https://doi.org/10.1021/ic700507j
F. A. Torralvo, C. Fernandez-Pereira and M. C. Campanario, Ind. Eng. Chem. Res. 49, 4817 (2010). https://doi.org/10.1021/ie901020f
S. Jagatap, S. Kolekar, S. Han, et al., Inter. J. Anal. Bioanal. Chem. 2, 235 (2012). http://www.urpjournals.com.
K. T. Mahmudov, R. A. Aliyeva, S. Z. Hamidov, et al., Am. J. Anal. Chem. 3, 790 (2012). https://doi.org/10.4236/ajac.2012.312105
H. Şenöz, Hacettepe J. Biol. Chem. 40, 293 (2012)
K. Stojnova, V. Divarova, P. Racheva, et al., Monatsh. Chem. 146, 867 (2015). https://doi.org/10.1007/s00706-014-1402-7
V. Divarova, K. Stojnova, P. Racheva, et al., Russ. J. Inorg. Chem. 60, 1374 (2015). https://doi.org/10.1134/S0036023615110030
K. Stojnova, V. Divarova, P. Racheva, et al., J. Appl. Spectrosc. 82, 85 (2015). https://doi.org/10.1007/s10812-015-0193-x
V. Divarova, K. Stojnova, P. Racheva, et al., Acta Chim. Slov. 63, 97 (2016). https://doi.org/10.17344/acsi.2015.1987
K. Stojnova, P. Racheva, V. Divarova, et al., Russ. J. Inorg. Chem. 62, 249 (2017). https://doi.org/10.1134/S0036023617020188
V. Divarova, K. Stojnova, P. Racheva, et al., Russ. J. Inorg. Chem. 63, 974 (2018). https://doi.org/10.1134/S0036023618070057
T. P. Rao, M. L. P. Reddy, A. R. Pillai, Talanta 46, 765 (1998). https://doi.org/10.1016/S0039-9140(97)00262-2
A. N. Turanov, V. K. Karandashev, V. E. Baulin, et al., Russ. J. Inorg. Chem. 61, 1335 (2016). https://doi.org/10.1134/S0036023616100211
A. N. Turanov, V. K. Karandashev, O. I. Artyushin, et al., Solvent Extr. Ion Exch. 33, 540 (2015). https://doi.org/10.1080/07366299.2015.1067052
G. Kristian, Analytical Chemistry (BINOM, Moscow, 2009).
M. I. Bulatov and I. P. Kalinkin, Practical Handbook on Photometric Methods of Analysis (Khimiya, Leningrad, 1986).
Funding
The authors would like to thank the Research Fund of the University of Plovdiv for the financial support of the current research.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Stojnova, K.T., Lekova, V.D. Study on the Equilibria of Chelate Formation and the Ion-association of Anionic Chelate of Germanium(IV) with 4-Nitrocatechol and 2-(4-Iodophenyl)-3-(4-nitrophenyl)-5-phenyl-2H-tetrazolium Cation. Russ. J. Inorg. Chem. 64, 1235–1241 (2019). https://doi.org/10.1134/S0036023619100152
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023619100152