Skip to main content
SpringerLink
Log in

Phase Formation in the Ternary System Nd2S3–Ga2S3–EuS

  • PHYSICOCHEMICAL ANALYSIS OF INORGANIC SYSTEMS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The ternary system Nd2S3–Ga2S3–EuS was studied by physicochemical analysis methods. The projection of the liquidus surface was constructed, and the boundaries of the glass formation region were found. It was determined that the ternary system consists of ten fields of primary crystallization of individual phases and the glass formation region. The thermolysis of the synthesized glasses was investigated, and their IR spectra were recorded. In the course of the thermolysis in an inert atmosphere, the glass (Ga2S3)0.70(Nd2S3)0.25(EuS)0.05 softens at 1010 K and then crystallizes at 1110 K. The mass loss proves that the exothermic events observed in the temperature range 1145–1225 K are related to stage-by-stage glass decomposition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. A. V. Kertman, Soros. Obraz. Zh. 6, 93 (2000).

    Google Scholar 

  2. Yu. S. Tveryanovich, Glass Phys. Chem. 29, 166 (2003).

    Article  CAS  Google Scholar 

  3. E. N. Borisov, V. B. Smirnov, A. S. Tveryanovich, and Yu. S. Tveryanovich, J. Non-Cryst. Solids, 326–327, 316 (2003).

    Article  CAS  Google Scholar 

  4. N. V. Kychkova, Candidate’s Dissertation in Chemistry (Tyumen’, 2006).

  5. S. A. Kozyukhin, Candidate’s Dissertation in Chemistry (Moscow, 2007).

  6. T. Yu. Ivanova, A. A. Man’shina, A. V. Kurochkin, et al., J. Non-Cryst. Solids 298, 7 (2002).

    Article  CAS  Google Scholar 

  7. K. D. Tsendin and N. A. Bogolovskiy, Semiconductors 46, 559 (2012).

    Article  CAS  Google Scholar 

  8. A. S. Vasilyeva, E. N. Borisov, S. A. Klotchenko, et al., Glass Phys. Chem. 40, 467 (2014).

    Article  CAS  Google Scholar 

  9. A. A. Man’shina, A. V. Kurochkin, S. V. Degtyarev, et al., Proc. SPIE—Int. Soc. Opt. Eng. 4429, 80 (2001).

  10. O. M. Aliev, O. A. Aliev, and P. G. Rustamov, Izv. Akad. Nauk SSSR, Neorg. Mater., No. 1, 22 (1987).

  11. S. Barnier and M. Guittard, C. R. Acad. Sci. C 282, 461 (1976).

    CAS  Google Scholar 

  12. A. V. Ruseikina and O. V. Andreev, Physicochemical Analysis of Natural and Technical Systems (Tyumensk. Gos. Univ, Tyumen’, 2008), p. 127.

  13. I. B. Bakhtiyarly, R. I. Kerimov, R. D. Kurbanova, and N. R. Akhmedova, Russ. J. Inorg. Chem. 59, 524 (2014).

    Article  CAS  Google Scholar 

  14. I. B. Bakhtiyarly, R. D. Kurbanova, R. I. Kerimov, et al., in Proceedings of the XIX International Conference “Physics of Strength and Plasticity of Materials,” Samara, Russia, June 8–11, 2015, p. 224 [in Russian].

  15. I. B. Bakhtiyarly, A. S. Abdullayeva, R. J. Kurbanova, et al., Azerbaijan Chem. J, No. 3, 113 (2016).

  16. R. I. Kerimov, Doctoral Dissertation in Chemistry (Inst. Chem. Additives, Natl. Acad. Sci. Azerbaijan, Baku, 2011).

  17. I. Goodyear and G. A. Steigmann, Acta Crystallogr. 16, 946 (1963).

    Article  CAS  Google Scholar 

  18. J. W. E. Drewitt, P. S. Salmon, A. Zeidler, et al., J. Phys.: Condens. Matter 29, 225 703 (2017).

    Google Scholar 

  19. S. Sagadevan and E. Chandraseelan, Int. J. ChemTech. Res. 6, 4682 (2014).

    CAS  Google Scholar 

  20. Q. Guoshun, L. Changgui, L. Zhuobin, et al., Infrared Phys. Technol. 63, 184 (2014).

    Article  CAS  Google Scholar 

  21. E. I. Yarembash and A. A. Eliseev, Rare-Earth Element Chalcogenides (Nauka, Moscow, 1975).

    Google Scholar 

  22. I. B. Bakhtiyarly, A. S. Abdullaeva, A. M. Mirzoeva, et al., Azerb. Khim. Zh., No. 3, 82 (2012).

Download references

Author information

Authors and Affiliations

  1. Nagiev Institute of Catalysis and Inorganic Chemistry, National Academy of Sciences of Azerbaijan, AZ1143, Baku, Azerbaijan

    I. B. Bakhtiyarly, R. D. Kurbanova, A. S. Abdullaeva, A. B. Aliev & F. M. Mamedova

Authors
  1. I. B. Bakhtiyarly
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. D. Kurbanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Abdullaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. B. Aliev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. M. Mamedova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to I. B. Bakhtiyarly or A. S. Abdullaeva.

Additional information

Translated by V. Glyanchenko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bakhtiyarly, I.B., Kurbanova, R.D., Abdullaeva, A.S. et al. Phase Formation in the Ternary System Nd2S3–Ga2S3–EuS. Russ. J. Inorg. Chem. 64, 890–893 (2019). https://doi.org/10.1134/S0036023619070039

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023619070039

Keywords:

Search

Navigation