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Synthesis and Study of (Sr,La)2FeCo0.5Mo0.5O6 − δ Oxides with Double Perovskite Structure

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Abstract

Complex oxides Sr2 − xLaxFeCo0.5Mo0.5O6 − δ, (x = 0.2, 0.4; δ ≈ 0.03–0.15) have been first synthesized by the sol-gel method. Their crystal structures have been refined by the Rietveld method; the refinement showed that the complex oxides have the structure of cubic double perovskite (a ≈ 2aper, space group Fm3̄m) with partial ordering of Fe(Co) and Mo in the B positions. Based on the 57Fe Mössbauer measurements, the average formal oxidation state of iron has been found to decrease from +3.20 (x = 0.0) to +3.04 (x = 0.4). Our study of the behavior of perovskites in a reducing Ar/H2 atmosphere (8%) revealed a decrease in the reduction resistance with decreasing La content (x = 0.4 → 0). The combination of the properties studied, namely chemical stability with respect to the reaction with Ce1 − xGdxO2 − x/2 and Zr1 − xYxO2 − x/2, high-temperature thermal expansion, and electrical conductivity in air and Ar/H2, shows that Sr1.6La0.4Fe-Co0.5Mo0.5O6 − δ (δ ≈ 0.03) perovskite is more attractive as an electrode material for medium-temperature symmetric solid oxide fuel cells than Sr2FeCo0.5Mo0.5O6 − δ.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119192, Russia

    M. M. Abdullaev, S. Ya. Istomin, A. V. Sobolev, I. A. Presnyakov & E. V. Antipov

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  1. M. M. Abdullaev
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  2. S. Ya. Istomin
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  3. A. V. Sobolev
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  4. I. A. Presnyakov
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  5. E. V. Antipov
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Correspondence to S. Ya. Istomin.

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Russian Text © The Author(s), 2019, published in Zhurnal Neorganicheskoi Khimii, 2019, Vol. 64, No. 6, pp. 572–580.

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Abdullaev, M.M., Istomin, S.Y., Sobolev, A.V. et al. Synthesis and Study of (Sr,La)2FeCo0.5Mo0.5O6 − δ Oxides with Double Perovskite Structure. Russ. J. Inorg. Chem. 64, 696–704 (2019). https://doi.org/10.1134/S0036023619060032

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  • DOI: https://doi.org/10.1134/S0036023619060032

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