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Structural Features of Mononuclear Chelate Dioxomolybdenum(VI) Complexes with Tetradentate Chelate Ligands—Schiff Bases, Salicylaldehyde Derivatives [MOO2(Lm)] (m = 1−11)

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Abstract

The structural features of 12 chelate complexes with the general formula [MoO2(Lm)], where Lm is a tetradentate chelate (N, N, O, O) ligand representing a Schiff base, a salicylaldehyde derivative (m = 1−11), have been considered. In all 12 complexes, the molybdenum atom has a cis,cis,cis-octahedral coordination. Both pairs of N(Lm), O(Lm) atoms occupy both trans- and cis-positions to oxo ligands.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. S. Sergienko

  2. All-Russian Institute for Scientific and Technical Information, Moscow, 125190, Russia

    V. S. Sergienko

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  1. V. S. Sergienko
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Correspondence to V. S. Sergienko.

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Sergienko, V.S. Structural Features of Mononuclear Chelate Dioxomolybdenum(VI) Complexes with Tetradentate Chelate Ligands—Schiff Bases, Salicylaldehyde Derivatives [MOO2(Lm)] (m = 1−11). Russ. J. Inorg. Chem. 64, 36–40 (2019). https://doi.org/10.1134/S0036023619010182

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  • DOI: https://doi.org/10.1134/S0036023619010182

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