Abstract
The structural chemistry of lithium intermetallic compounds that are formed in Li–М binary systems where М = Ca, Sr, Ba, Mg, Zn, Cd, and Hg is surveyed. It is for the first time that the crystal structures of intermetallic compounds are classified in terms of polyhedral precursor metal clusters (in the program package ToposPro). The precursor metal clusters of crystal structures are identified using the algorithms of partitioning structural graphs into cluster structures and via the design of the basal 3D network of the structure in the form of a graph whose nodes correspond to the positions of the centers of precursor clusters. Tetrahedral precursor metal clusters M4 are identified for the crystal structures LiZn3-oC4, LiMg3-hP2, LiCd3-hP2, LiHg3-hP8, (LiMg3)(Li2Mg2)-tI16, Li2Zn2-cF16, Li2Cd2-cF16, Li2Hg2-cP2, Li3Cd-cF4, and Li3Hg-cF16; tetrahedral metal clusters M4 are found for the framework structures with spacer atoms Sr(Li2Sr2)-tP20, Ca2(Li4)-cF24, and Ca2(Li4)-cP12; tetrahedral metal clusters M4 and rings M6, for framework structures Ba3Li2(Li10)-hP30 and Ba3Li2(Li4In6)-hP30; icosahedral metal clusters M13 for the framework structure Li(Zn13)-cF112; bilayer tetrahedral metal clusters 0@М4@M22 for the framework structure Li23Sr6-cF116; and deltahedra М17 and deltahedra М30, for framework structures Sr4Li14 [Sr(Sr4Li12)] [(Sr2 (Sr8Li18)]-tI252 and Ba4Li14 [Ba(Ba4Li12)][(Ba2 (Ba8Li18)]-tI252. The scenario of crystal structure self-assembly from precursor metal clusters S30 in intermetallic compounds is reconstituted as: primary chain S31→ microlayer S32→ microframework S33.
Similar content being viewed by others
References
P. Villars and K. Cenzual, Pearson’s Crystal Data-Crystal Structure Database for Inorganic Compounds (PCDIC) (Materials Park, OH, ASM).
Inorganic Crystal Structure Database (ICSD) (Fachinformationszentrum, Karlsruhe).
W. Pearson, The Crystal Chemistry and Physics of Metals and Alloys (Wiley, New York, 1972).
A. I. Kitaigorodskii, Mixed Crystals (Nauka, Moscow, 1983) [in Russian].
A. F. Wells, Structural Inorganic Chemistry (Oxford Univ. Press, London, 1984).
P. I. Kripyakevich, Structure Types of Intermetallic Compounds (Nauka, Moscow, 1977) [in Russian]
T. G. Akhmetshina, V. A. Blatov, D. M. Proserpio, and A. P. Shevchenko, Acc. Chem. Res. 51, 21 (2018). doi 10.1021/acs.accounts.7b00466
A. A. Pankova, T. G. Akhmetshina, V. A. Blatov, and D. M. Proserpio, Inorg. Chem. 54, 6616 (2015). doi 10.1021/acs.inorgchem.5b00960
J. Dshemuchadse and W. Steurer, Inorg. Chem. 54, 1120 (2015). doi 10.1021/ic5024482
J. Dshemuchadse and W. Steurer, Acta Crystallorg., Sect. A 71, 335 (2015). doi 10.1107/S2053273315004064
G. D. Ilyushin, Crystallogr. Repts. 62, 670 (2017). doi 10.1134/S106377451705008X
G. D. Ilyushin, Crystallogr. Repts. 63, 543 (2018). doi 10.1134/S1063774518040089
G. D. Ilyushin, Russ. J. Inorg. Chem. 62, 1730 (2017). doi 10.1134/S0036023617130046
V. A. Blatov, A. P. Shevchenko, and D. M. Proserpio, Cryst. Growth Des. 14, 3576 (2014). doi 10.1021/cg500498k
G. D. Ilyushin, Modeling of Self-Organization Processes in Crystal-Forming Systems (URSS, Moscow, 2003) [in Russian].
G. D. Ilyushin, Struc. Chem. 20, 975 (2012). doi 10.1007/s11224-012-0014-2
G. D. Ilyushin, Russ. J. Inorg. Chem. 61, 1727 (2016). doi 10.1134/S0036023616140023
A. Pankova, V. Blatov, G. Ilyushin, and D. Proserpio, Inorg. Chem. 52, 13094 (2013). doi 10.1021/ic4019713
V. A. Blatov, G. D. Ilyushin, and D. M. Proserpio, Chem. Mater. 25, 412 (2013). doi 10.1021/cm303528u
V. A. Blatov, G. D. Ilyushin, and D. M. Proserpio, Inorg. Chem. 49, 1811 (2010). doi 10.1021/ic9021933
B. Olinger and J.W. Shaner, Science 219, 1971 (1983). doi 10.1126/science.219.4588.1071
C. S. Barrett, Acta Cryst. 9, 671 (1956). doi 10.1107/S0365110X56001790
R. W. Lynch and H. G. J. Drickamer, Phys. Chem. Solids 26, 63 (1965). doi 10.1016/0022-3697(65)90073-9
C. B. Walker and M. Marezio, Acta Metall. 7, 769 (1959). doi 10.1016/0001-6160(59)90090-2
R. S. Amand and B. C. Giessen, J. Less-Common Met. 58, 161 (1978). doi 10.1016/0022-5088(78)90197-2
M. Hanfland, K. Syassen, N. E. Christensen, and D. L. Novikov, Nature 408, 174 (2000). doi 10.1038/35041515
V. Pavlyuk, I. Chumak, L. Akselrud, S. Lidin, H. Ehrenberg, Acta Cryst., Sect. B 70, 212 (2014). doi 10.1107/S2052520613030709
N. Vigier, A. C. Den, C. Fillaux, et al., Chem. Mater. 20, 3199 (2008). doi 10.1021/cm8001783
N. Karlsson, J. Inst. Metals 79, 391 (1951).
J. Huot, S. Bouaricha, S. Boily, et al., J. Alloys Compd. 266, 307 (1998). doi 10.1016/S0925-8388(97)00440-4
E. Zintl and A. Schneider, Z. Elektrochem. 41, 294 (1935).
E. Zintl and A. Schneider, Z. Elektrochem. Ang. Phys. Chem. 41, 771 (1935).
F. H. Herbstein and B. L. Averbach, Acta Crystallogr. 9, 91 (1956).
K. Kuriyama, S. Saito, and K. Iwamura, J. Phys. Chem. Solids 40, 457 (1979). doi 10.1016/0022-3697(79)90062-3
M. Zwilling, P. C. Schmidt, and A. Weiss, Apppl. Phys. 16, 255 (1978). doi 10.1007/BF00885121
H. Pauly, A. Weiss, and H. Witte, Z. Metall. 59, 554 (1968).
V. Smetana, L. Kienle, V. Duppel, and A. Simon, Inorg. Chem. 54, 733 (2015). doi 10.1021/ic5010165
D. Fischer and M. Z. Jansen, Anorg. Allg. Chem. 629, 1934 (2003). doi 10.1002/zaac.200300179
R. Nesper and G. J. Miller, J. Alloys Compd 197, 109 (1993). doi 10.1016/0925-8388(93)90628-Z
V. Smetana, V. Babizhet’sky, C. Hoch, and A. Simon, Z. Kristallogr. 221, 434 (2006). doi 10.1524/ncrs.2006.0142
V. Smetana, G. V. Vajenine, L. Kienle, V. Duppel, A. J. Simon, Solid State Chem. 183, 1767 (2010). doi 10.1016/j.jssc.2010.05.021
D. Fischer and M. Z. Jansen, Anorg. Allg. Chem. 636, 1917 (2010). doi 10.1002/zaac.201000222
M. Wendorff and C. Roehr, J. Alloys Compd 421, 24 (2006). doi 10.1016/j.jallcom.2005.11.016
F. E. Wang, A. J. King, and F. A. J. Kanda, Phys. Chem. 66, 2142 (1962). doi 10.1021/j100817a016
V. Smetana, V. Babizhet’sky, G. V. Vajenine, C. Hoch, and A. Simon, Inorg. Chem. 46, 5425 (2007). doi 10.1021/ic070249i
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ilyushin, G.D. Crystal Chemistry of Lithium Intermetallic Compounds: A Survey. Russ. J. Inorg. Chem. 63, 1796–1811 (2018). https://doi.org/10.1134/S0036023618140024
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023618140024