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Titanium Carbohydride Synthesis by Mechanical Activation in Liquid Hydrocarbon

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Mechanical activation of titanium in petroleum ether with subsequent heat treatment produced titanium carbohydrides with hexagonal close-packed and face-centered cubic lattices. The effect of iron and copper additions on the structural and phase composition of the titanium-based powders after the mechanical activation and heat treatment was studied. In these systems, both titanium carbohydrides, and the intermetallics Ti–Cu, Ti–Fe, and Ti–Fe–Cu formed. All the obtained powders contained ~1 wt % hydrogen. The release of hydrogen by heating the powders was investigated, and the lowest release temperatures (220–500°C) were detected for the phase Ti–Fe–Cu.

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Authors and Affiliations

  1. Udmurt Federal Research Center, Ural Branch, Russian Academy of Sciences, Izhevsk, 426067, Russia

    M. A. Eremina, S. F. Lomaeva, I. N. Burnyshev, D. G. Kalyuzhnyi & G. N. Konygin

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  1. M. A. Eremina
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  2. S. F. Lomaeva
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  3. I. N. Burnyshev
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  4. D. G. Kalyuzhnyi
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  5. G. N. Konygin
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Correspondence to M. A. Eremina.

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Original Russian Text © M.A. Eremina, S.F. Lomaeva, I.N. Burnyshev, D.G. Kalyuzhnyi, G.N. Konygin, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 10, pp. 1257–1265.

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Eremina, M.A., Lomaeva, S.F., Burnyshev, I.N. et al. Titanium Carbohydride Synthesis by Mechanical Activation in Liquid Hydrocarbon. Russ. J. Inorg. Chem. 63, 1274–1282 (2018). https://doi.org/10.1134/S0036023618100066

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  • DOI: https://doi.org/10.1134/S0036023618100066

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