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BIFEVOX Composites: Manufacture and Characterization

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Design of composites is a way to improve the quality of solid electrolytes. By mechanically mixing and annealing substituted bismuth vanadate with nanosized aluminum, bismuth, and zirconium binary oxides, we obtained heterogeneous materials Bi4V1.7Fe0.3O11 – δ/xAl2O3, Bi4V1.7Fe0.3O11 – δ/xBi2O3, and Bi4V1.7Fe0.3O11 – δ/xYSZ. The investigation tools were X-ray powder diffraction and electron microscopy with energy-dispersive microanalysis. The composition of materials was studied, the non-interaction of components was elucidated in the aluminum oxide and zirconium oxide composite series, and a nonuniform distribution of nanopowder particles across the surfaces and cleaves of sinters was discovered. The bismuth atoms from bismuth oxide were shown to be capable of incorporating into the Bi4Fe0.3V1.7O11 – δ structure. The charge transport characteristics of the materials were studied by impedance spectroscopy. No changes were observed in logσ–103/T trends in composites with various binary oxides and various oxide contents. An increase in binary oxide concentration was shown to give rise to an insignificant decay in electrical conductivity.

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Authors and Affiliations

  1. Ural Federal University, Yekaterinburg, 620002, Russia

    E. S. Buyanova, Yu. V. Emel’yanova, M. V. Morozova, A. A. Krylov & I. V. Nikolaenko

  2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    I. V. Nikolaenko

Authors
  1. E. S. Buyanova
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  2. Yu. V. Emel’yanova
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  3. M. V. Morozova
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  4. A. A. Krylov
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  5. I. V. Nikolaenko
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Correspondence to E. S. Buyanova.

Additional information

Original Russian Text © E.S. Buyanova, Yu.V. Emel’yanova, M.V. Morozova, A.A. Krylov, I.V. Nikolaenko, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 10, pp. 1280–1285.

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Buyanova, E.S., Emel’yanova, Y.V., Morozova, M.V. et al. BIFEVOX Composites: Manufacture and Characterization. Russ. J. Inorg. Chem. 63, 1297–1302 (2018). https://doi.org/10.1134/S0036023618100042

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  • DOI: https://doi.org/10.1134/S0036023618100042

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