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Onium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and Aniline

  • Physical Methods of Investigation
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Abstract

The reaction products formed in the SO2–L–H2O–O2 systems (L is n-propylamine, n-butylamine, tert-butylamine, n-heptylamine, n-octylamine, aniline) were isolated and identified as “onium” salts [n-C3H7NH3]2SO4, [n-C4H9NH3]2SO4, [t-C4H9NH3]2SO4, [n-C7H15NH3]3SO4(HSO4), [n-C8H17NH3]3SO4(HSO4), and [C6H5NH3]2SO4. The products were characterized by elemental analysis, IR and Raman spectroscopy, mass spectrometry, and thermogravimetry.

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Authors and Affiliations

  1. Physical Chemical Institute for Environment and Human Protection, MES and NAS of Ukraine, Odessa, 65082, Ukraine

    R. E. Khoma, A. A. Ennan & R. M. Dlubovskii

  2. Odessa Mechnikov National University, Odessa, 65082, Ukraine

    R. E. Khoma

  3. Odessa National Medical University, Odessa, 65082, Ukraine

    V. O. Gel’mbol’dt

  4. NTK Institute of Single Crystals, National Academy of Sciences of Ukraine, Kharkiv, 61001, Ukraine

    V. N. Baumer

  5. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, 65080, Ukraine

    I. M. Rakipov

Authors
  1. R. E. Khoma
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  2. V. O. Gel’mbol’dt
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  3. A. A. Ennan
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  4. V. N. Baumer
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  5. I. M. Rakipov
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  6. R. M. Dlubovskii
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Correspondence to R. E. Khoma.

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Original Russian Text © R.E. Khoma, V.O. Gel’mbol’dt, A.A. Ennan, V.N. Baumer, I.M. Rakipov, R.M. Dlubovskii, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 625–630.

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Khoma, R.E., Gel’mbol’dt, V.O., Ennan, A.A. et al. Onium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and Aniline. Russ. J. Inorg. Chem. 63, 655–660 (2018). https://doi.org/10.1134/S0036023618050157

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  • DOI: https://doi.org/10.1134/S0036023618050157

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