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Effects of the Nature of Transition Metal on the Composition and Structure of Reaction Products of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (М = Cu(II), Ni(II), Co(II), or Mn(II)) with 1,10-Phenanthroline

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Abstract

Reactions of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (M = Ni(II), Co(II), or Mn(II)) adducts with 1,10-phenanthroline in chloroform at room temperature are found to yield complexes Phen n M[(OOCC5H4) Mn(CO)3]2 (Co(II) or Mn(II), n = 2; M = Ni(II), n = 3). A similar reaction of dimeric Cu2[μ-(OOCC5H4) Mn(CO)3]4[O(H)Me]2 yields mononuclear PhenCu[(OOCC5H4)Mn(CO)3][O(H)Me] · MeOH. The resulting complexes are isolated in high yields and characterized by chemical analysis, IR spectroscopy, and X-ray crystallography.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Grineva, M. A. Uvarova, R. R. Datchuk & S. E. Nefedov

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  1. A. A. Grineva
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  2. M. A. Uvarova
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  3. R. R. Datchuk
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  4. S. E. Nefedov
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Correspondence to S. E. Nefedov.

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Original Russian Text © A.A. Grineva, M.A. Uvarova, R.R. Datchuk, S.E. Nefedov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 579–586.

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Grineva, A.A., Uvarova, M.A., Datchuk, R.R. et al. Effects of the Nature of Transition Metal on the Composition and Structure of Reaction Products of M[(OOCC5H4)Mn(CO)3]2[O(H)Me]4 (М = Cu(II), Ni(II), Co(II), or Mn(II)) with 1,10-Phenanthroline. Russ. J. Inorg. Chem. 63, 610–617 (2018). https://doi.org/10.1134/S0036023618050091

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  • DOI: https://doi.org/10.1134/S0036023618050091

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