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Chemical Processes in Systems CuI(CuII)/L/[B12H12]2–/solv (L = bipy, phen; solv = CH3CN, DMF, and CH2I2)

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Abstract

Processes proceeding in the CuI(CuII)/L/(L = bipy, phen) systems in the presence of the [B12H12]2– anion, which has the lowest reduction ability among the boron cluster anions [B n H n ]2– (n = 6, 10, 12), have been studied. It has been found that the preparation of CuI and heterovalent CuI/CuII complexes with azaheterocyclic ligands and the [B12H12]2–anion requires the CuII reduction process to be initiated. To minimize the redox process in the CuI/L/[B12H12]2– system, redox-active starting components have been added to the reaction system. Mono- and polynuclear copper complexes with various composition and structures have been isolated as a result of redox reactions proceeding in the CuI(CuII)/L/[B12H12]2–/solv (L = bipy, phen; solv = CH3CN, DMF, CH2I2) systems.

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References

  1. A. E. Dziova, V. V. Avdeeva, I. N. Polyakova, et al., Dokl. Ross. Akad. Nauk 442, 57 (2012).

    Google Scholar 

  2. V. V. Avdeeva, A. E. Dziova, I. N. Polyakova, et al., Dokl. Ross. Akad. Nauk 437, 488 (2011).

    Google Scholar 

  3. V. V. Avdeeva, A. E. Dziova, I. N. Polyakova, et al., Russ. J. Inorg. Chem. 58, 657 (2013).

    Article  CAS  Google Scholar 

  4. V. V. Avdeeva, A. E. Dziova, I. N. Polyakova, et al., Inorg. Chim. Acta 430, 74 (2015).

    Article  CAS  Google Scholar 

  5. A. E. Dziova, V. V. Avdeeva, I. N. Polyakova, et al., Russ. J. Inorg. Chem. 59, 51 (2014).

    Google Scholar 

  6. N. N. Greenwood and J. H. Morris, Proc. Chem. Soc. 11, 338 (1963).

    Google Scholar 

  7. E. A. Malinina, V. V. Drozdova, V. N. Mustyatsa, et al., Russ. J. Inorg. Chem. 51, 1723 (2006).

    Article  Google Scholar 

  8. V. V. Drozdova, E. A. Malinina, O. N. Belousova, et al., Russ. J. Inorg. Chem. 53, 1024 (2008).

    Article  Google Scholar 

  9. E. A. Malinina, K. Yu. Zhizhin, I. N. Polyakova, et al., Russ. J. Inorg. Chem. 47, 1275 (2002).

    CAS  Google Scholar 

  10. A. E. Dziova, V. V. Avdeeva, I. N. Polyakova, et al., Dokl. Ross. Akad. Nauk 440, 351 (2011).

    Google Scholar 

  11. M. Odoko, Y. Wang, and N. Okabe, Acta Crystallogr., Sect E: Struct. Rep. Online 60, M1522 (2004).

    Article  CAS  Google Scholar 

  12. E. A. Malinina, I. K. Kochneva, I. N. Polyakova, et al., Inorg. Chim. Acta (2018). doi.org/10.1016/j.ica. 2018.03.024

    Google Scholar 

  13. L. I. Ochertyanova, V. N. Mustyatsa, K. Yu. Zhizhin, et al., Inorg. Mater. 40, 144 (2004).

    Article  CAS  Google Scholar 

  14. V. K. Kochnev, V. V. Avdeeva, E. A. Malinina, and N. T. Kuznetsov, Russ. J. Inorg. Chem. 59, 1268 (2014).

    Article  CAS  Google Scholar 

  15. I. K. Kochneva, I. N. Polyakova, V. V. Avdeeva, et al., Dokl. Ross. Akad. Nauk 474, 581 (2017).

    Google Scholar 

  16. N. Chaozhou, M. Yilin, and S. Cuifang, Acta Chim. Sin. 43, 411 (1985).

    Google Scholar 

  17. J. T. Gill and S. J. Lippard, Inorg. Chem. 14, 751 (1975).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    I. K. Kochneva, V. V. Avdeeva, L. V. Goeva, E. A. Malinina & N. T. Kuznetsov

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  1. I. K. Kochneva
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  2. V. V. Avdeeva
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  3. L. V. Goeva
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  4. E. A. Malinina
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  5. N. T. Kuznetsov
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Corresponding author

Correspondence to I. K. Kochneva.

Additional information

Original Russian Text © I.K. Kochneva, V.V. Avdeeva, L.V. Goeva, E.A. Malinina, N.T. Kuznetsov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 559–565.

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Kochneva, I.K., Avdeeva, V.V., Goeva, L.V. et al. Chemical Processes in Systems CuI(CuII)/L/[B12H12]2–/solv (L = bipy, phen; solv = CH3CN, DMF, and CH2I2). Russ. J. Inorg. Chem. 63, 591–596 (2018). https://doi.org/10.1134/S0036023618050066

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  • DOI: https://doi.org/10.1134/S0036023618050066

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