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Russian Journal of Inorganic Chemistry

, Volume 63, Issue 3, pp 343–348 | Cite as

μ2-Oxobis[(aroxo)tris(para-tolyl)antimony]: Synthesis and Structure

  • V. V. Sharutin
  • O. K. Sharutina
  • A. N. Efremov
Coordination Compounds
  • 15 Downloads

Abstract

µ2-Oxobis[(2,4,6-tribromophenoxo)tris(para-tolyl)antimony] (I), µ2-oxobis[(2,3,4,5,6-pentachlorophenoxo) tris(para-tolyl)antimony] (II), and µ2-oxobis(2,4-dinitrophenoxo)tris(para-tolyl)antimony] (III) have been synthesized with high yields by the reaction of tris(para-tolyl)antimony with 2,4,6-tribromo-, 2,3,4,5,6-pentachloro-, and 2,4-dinitrophenol, respectively, in ether in the presence of tert-butylhydroperoxide. The Sb atoms in complexes I, II, and III have a distorted trigonal bipyramidal coordination with the aroxyl ligands and the bridging oxygen atom in axial positions. The central Sb–O–Sb moiety in molecules of complexes I–III has an angular structure.

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Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • V. V. Sharutin
    • 1
  • O. K. Sharutina
    • 1
  • A. N. Efremov
    • 1
  1. 1.National South Ural State Research UniversityChelyabinskRussia

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