Russian Journal of Inorganic Chemistry

, Volume 63, Issue 3, pp 391–399 | Cite as

Porphyrin–Fullerene Dyad Based on Indium(III) Complex. Donor–Acceptor Complex Formation Equilibrium

  • E. N. Ovchenkova
  • N. G. Bichan
  • T. N. Lomova
Physical Chemistry of Solutions


Formation kinetics and spectral properties of the donor–acceptor complexes of (5,10,15,20- tetra(2-methoxyphenyl)porphinato)chloroindium(III) with 2′-(pyridin-4-yl)-5′-(pyridin-2-yl)-1′-(pyridin- 2-yl)methylpyrrolidinyl[3′,4′:1,2][60]fullerene were studied. The formation of the donor–acceptor dyad [(Py3F)InTPP(2-OCH3)4]+Cl occurs as a two-step reaction, including fast reversible coordination of the fullerene base molecule and slow irreversible displacement of the axial chloride ion to the second coordination sphere. Quantitative characteristics for the reaction rate and equilibrium were obtained. The reaction products were identified by IR and 1H NMR spectroscopy. The most important electron optical and stability parameters of the porphyrin–fullerene dyads with inner- and outer-sphere chloride ions were determined. These results are important for studies of the photophysics of porphyrin–fullerene dyads and development of photoconverters based on them.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    M. H. Lee, J. W. Kim, and C. Y. Lee, J. Organomet. Chem. 761, 20 (2014).CrossRefGoogle Scholar
  2. 2.
    R. Koeppe, P. A. Troshin, A. Fuchsbauer, et al., Full. Nanotub. Carb. Nanostr. 14, 441 (2006).CrossRefGoogle Scholar
  3. 3.
    E. N. Ovchenkova, N. G. Bichan, and T. N. Lomova, Tetrahedron 71, 6659 (2015).CrossRefGoogle Scholar
  4. 4.
    H. Zhao, Y. Zhu, C. Chen, and J. Zheng, Polymer 55, 1913 (2014).CrossRefGoogle Scholar
  5. 5.
    RosT. Da, Prato. Maurizio, M. Carano, et al., J. Organomet. Chem. 599, 62 (2000).CrossRefGoogle Scholar
  6. 6.
    D. Gust, T. A. Moore, and A. L. Moore, J. Photochem. Photobiol., Ser. B: Biol. 58, 63 (2000).CrossRefGoogle Scholar
  7. 7.
    I. Bouamaied, T. Coskun, and E. Stulz, Struct. Bond 121, 1 (2006).CrossRefGoogle Scholar
  8. 8.
    J. Iehl, M. Urbani, and J.-F. Nierengarten, Handbook of Carbon Nano Materials, Ed. by F. D’Souza and K. M. Kadish (World Scientific, Singapore, 2011), Vol. 1, p.1.Google Scholar
  9. 9.
    A. S. D. Sandanayaka and O. Ito, J. Porph. Phthalocyan. 13, 1017 (2009).CrossRefGoogle Scholar
  10. 10.
    V. F. Razumov, V. V. Abalyaeva, O. N. Efimov, et al., Nanostructured Materials for Energy Accumulation and Conversion, Ed. by V. F. Razumov and M. V. Klyuev (Ivanovskii Gos. Univ., Ivanovo, 2009) [in Russian].Google Scholar
  11. 11.
    M. Yu. Tipugina and T. N. Lomova, Russ. J. Phys. Chem. 76, 567 (2002).Google Scholar
  12. 12.
    T. N. Lomova and B. D. Berezin, Russ. J. Coord. Chem. 19, 98 (1993).Google Scholar
  13. 13.
    T. N. Lomova, E. V. Motorina, and M. V. Klyuev, CRC Concise Encyclopedia of Nanotechnology, Ed. by B. I. Kharisov, O. V. Kharissova, and U. Ortiz-Mendez (CRC Press, Taylor and Francis Group, London, 2016), p. 215.Google Scholar
  14. 14.
    T. N. Lomova, M. E. Malov, M. V. Klyuev, and P. A. Troshin, Advances in Materials Science Research, Ed. by M. C. N. Y. Wythers (Nova Science Publ., New York, 2016).Google Scholar
  15. 15.
    V. A. Shorin, S. Maslennikov, M. I. Fedorov, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 42, 89 (1999).Google Scholar
  16. 16.
    P. A. Troshin, S. I. Troyanov, G. N. Boiko, et al., Full. Nanotub. Carb. Nanostr. 12, 413 (2004).CrossRefGoogle Scholar
  17. 17.
    E. V. Motorina, T. N. Lomova, P. A. Troshin, and M. V. Klyuev, Russ. J. Gen. Chem. 84, 946 (2014).CrossRefGoogle Scholar
  18. 18.
    P. A. Troshin, S. I. Troyanov, G. N. Boiko, et al., Full. Nanotub. Carb. Nanostr. 12, 435 (2004).Google Scholar
  19. 19.
    T. N. Lomova, E. G. Mozhzhukhina, L. P. Shormanova, and B. D. Berezin, Russ. J. Gen. Chem. 59, 2077 (1989).Google Scholar
  20. 20.
    P. A. Troshin, A. S. Peregudov, S. I. Troyanov, and R. N. Lyubovskaya, Russ. Chem. Bull. 57, 887 (2008).CrossRefGoogle Scholar
  21. 21.
    T. N. Lomova, M. E. Malov, M. V. Klyuev, and P. A. Troshin, Macroheterocycles 2, 164 (2009).CrossRefGoogle Scholar
  22. 22.
    T. N. Lomova, E. V. Motorina, and M. V. Klyuev, Macroheterocycles 6, 327 (2013).CrossRefGoogle Scholar
  23. 23.
    A. N. Lapshin, Extended Abstract of Candidate’s Dissertation in Chemistry (Chernogolovka, 2006).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • E. N. Ovchenkova
    • 1
  • N. G. Bichan
    • 1
  • T. N. Lomova
    • 1
  1. 1.Krestov Institute of Solution ChemistryRussian Academy of SciencesIvanovoRussia

Personalised recommendations