Russian Journal of Inorganic Chemistry

, Volume 63, Issue 3, pp 369–372 | Cite as

Luminescence and Structure of Potassium Fluorooxalatozirconates

  • M. M. GodnevaEmail author
  • N. N. Boroznovskaya
Physical Methods of Investigation


The X-ray luminescence of potassium fluorooxalatozirconates was studied. A high emission intensity was established for KZrF3C2O4 · 3H2O. Potassium fluorooxalatozirconates and fluorine compounds with known structures were compared by their X-ray luminescence. From the maximal luminescence intensity, it was established what atoms (F* or O*) were responsible for the luminescence of fluorooxalatozirconates. The composition of their polyhedra was suggested based on IR and X-ray luminescence spectra. It was shown that water in hydrated fluorooxalatozirconates has a crystallization character.


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  1. 1.
    M. M. Godneva and N. N. Boroznovskaya, Perspektivn. Mater., No. 6, 32 (2014).Google Scholar
  2. 2.
    M. M. Godneva, M. P. Rys’kina, V. Ya. Kuznetsov, and O. A. Zalkind, Russ. J. Inorg. Chem. 60, 347 (2015).CrossRefGoogle Scholar
  3. 3.
    R. L. Davidovich, I. G. Dergacheva, and S. B. Ivanov, Izv. Akad. Nauk SSSR, Ser. Khim., No. 12, 2653 (1975).Google Scholar
  4. 4.
    M. M. Godneva, O. A. Zalkind, and A. T. Belyaevskii, Zh. Strukt. Khim. 54, 651 (2013).Google Scholar
  5. 5.
    A. B. Slobodyuk, N. A. Didenko, and M. M. Godneva, J. Struct. Chem. 56, 1116 (2015).CrossRefGoogle Scholar
  6. 6.
    N. N. Boroznovskaya, M. M. Godneva, D. L. Motov, and V. M. Klimkin, Inorg. Mater. 43, 425 (2007).CrossRefGoogle Scholar
  7. 7.
    M. M. Godneva, D. L. Motov, N. N. Boroznovskaya, and V. M. Klimkin, Russ. J. Inorg. Chem. 52, 661 (2007).CrossRefGoogle Scholar
  8. 8.
    E. R. Gobetchia, Yu. K. Kabalov, V. I. Pet’kov, and M. V. Sukhanov, in Proceedings of the XV International Conference on X-ray Diffraction and Crystal Chemistry of Minerals (St. Petersburg, 2003), p. 90.Google Scholar
  9. 9.
    D. L. Rogachev, V. Ya. Kuznetsov, A. I. Gusev, and E. B. Chuklanova, Zh. Strukt. Khim. 30, 182 (1989).Google Scholar
  10. 10.
    A. S. Foster, F. L. Gejo, A. L. Schluger, and R. M. Nieminen, Phys. Rev. B 64, 224108 (2001).CrossRefGoogle Scholar

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© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  1. 1.Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Science CenterRussian Academy of SciencesApatity, Murmansk oblastRussia
  2. 2.National Research Tomsk State UniversityTomskRussia

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