Russian Journal of Inorganic Chemistry

, Volume 63, Issue 3, pp 308–313 | Cite as

Carbon-Supported Palladium–Gold Bimetallic Disperse Systems Formed in Aqueous Solutions at 110°С

  • R. V. Borisov
  • O. V. Belousov
  • A. M. Zhizhaev
  • N. V. Belousova
  • S. D. Kirik
Synthesis and Properties of Inorganic Compounds


Various palladium–carbon composites have been manufactured by autoclaving at 170°С to be used as precursors for manufacturing bimetallic particles. The morphology of the manufactured items was comprehensively studied by scanning electron microscopy; the ultrafine metal palladium was found to have particles sizes lying in the range 30–120 nm. The specifics of hydrothermal reduction of gold(III) chloro complexes by palladium–carbon composites at 110°С have been studied. An appreciable increase in gold(III) reduction rate was observed with the use of a palladium–carbon composite relative to the rate observed for ultrafine metallic palladium. Gold is reduced on a palladium–carbon composite to an individual metallic phase.


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  1. 1.
    A. Chen and C. Ostrom, Chem. Rev. 115, 11999 (2015).CrossRefGoogle Scholar
  2. 2.
    B. Wu and N. Zheng, Nano Today 8 (2), 168 (2013).CrossRefGoogle Scholar
  3. 3.
    G. Agostini, C. Lamberti, R. Pellegrini, et al., ACS Catal. 4, 187 (2013).CrossRefGoogle Scholar
  4. 4.
    V. B. Ukraintsev and K. A. Khokhryakov, Zhurn. Ros. Khim. O–va Im. D.I. Mendeleeva 50 (4), 154 (2006).Google Scholar
  5. 5.
    B. Wu, Y. Kuang, X. Zhang, and J. Chen, Nano Today 6 (1), 75 (2011).CrossRefGoogle Scholar
  6. 6.
    Z. Liu, L. Hong, M. P. Tham, et al., J. Power Sources 161, 831 (2006).CrossRefGoogle Scholar
  7. 7.
    H. R. Choi, H. Woo, S. Jang, et al., ChemCatChem 4, 1587 (2012).CrossRefGoogle Scholar
  8. 8.
    A. Bernas, I. L. Simakova, K. Eranen, et al., Catal. Ind. 2 (2), 95 (2010).CrossRefGoogle Scholar
  9. 9.
    R. Wang, Z. Wu, C. Chen, et al., Chem. Commun. 49, 8250 (2013).CrossRefGoogle Scholar
  10. 10.
    J. K. Edwards, J. Pritchard, M. Piccinini, et al., J. Catal. 292, 227 (2012).CrossRefGoogle Scholar
  11. 11.
    L. Peng, E. Ringe, R. P. Van Duyne, and L. D. Marks, Phys. Chem. Chem. Phys. 17, 27940 (2015).CrossRefGoogle Scholar
  12. 12.
    C. C. Kung, P. Y. Lin, Y. Xue, et al., J. Power Sources 256, 329 (2014).CrossRefGoogle Scholar
  13. 13.
    O. G. Ellert, M. V. Tsodikov, S. A. Nikolaev, and V.M. Novotortsev, Usp. Khim. 83, 718 (2014).CrossRefGoogle Scholar
  14. 14.
    N. L. Kovalenko, O. V. Belousov, and L. I. Dorokhova, Russ. J. Inorg. Chem. 47, 967 (2002).Google Scholar
  15. 15.
    N. V. Belousova, A. V. Sirotina, O. V. Belousov, and V. A. Parfenov, Russ. J. Inorg. Chem. 57, 15 (2012).CrossRefGoogle Scholar
  16. 16.
    E. V. Fesik, V. V. Grebnev, V. I. Zarazhevskii, and G. D. Mal’chikov, Zh. Prikl. Khim. 87, 601 (2014).Google Scholar
  17. 17.
    R. V. Borisov and O. V. Belousov, Zh. Sib. Fed. Univ. Khim. 7, 331 (2014).Google Scholar
  18. 18.
    N. L. Kovalenko, A. V. Vershkov, and G. D. Mal’chikov, Koord. Khim. 13, 554 (1987).Google Scholar
  19. 19.
    N. L. Kovalenko, N. Ya. Rogin, and G. D. Mal’chikov, Koord. Khim. 11, 1276 (1985).Google Scholar
  20. 20.
    Synthesis of Platinum Metal Complexes. Handbook, Ed. by I. I. Chernyaev (Nauka, Moscow, 1964) [in Russian].Google Scholar
  21. 21.
    A. G. Tkachev, Perspektivn. Mater. 3, 5 (2007).Google Scholar
  22. 22.
    O. V. Belousov, A. V. Sirotina, N. V. Belousova, et al., Zh. Sib. Fed. Univ. Tekh. Tekhnol. 7, 138 (2014).Google Scholar
  23. 23.
    O. V. Belousov, N. V. Belousova, A. V. Sirotina, et al., Langmuir 27, 11697 (2011).CrossRefGoogle Scholar
  24. 24.
    O. V. Belousov, L. I. Dorokhova, L. A. Solov’ev, and S. M. Zharkov, Zh. Fiz. Khim. 81, 1479 (2007).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2018

Authors and Affiliations

  • R. V. Borisov
    • 1
  • O. V. Belousov
    • 1
  • A. M. Zhizhaev
    • 1
  • N. V. Belousova
    • 2
  • S. D. Kirik
    • 2
  1. 1.Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of SciencesKrasnoyarsk Scientific Center of Siberian Branch of the Russian Academy of SciencesKrasnoyarskRussia
  2. 2.Siberian Federal UniversityKrasnoyarskRussia

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