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Scheelite-Related Triple Molybdates KCaLn(MoO4)3 in K2MoO4–CaMoO4–Ln2(MoO4)3 (Ln = Nd, Sm, Eu, Gd) Systems: Synthesis and Characterization

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Subsolidus phase ratios in K2MoO4–CaMoO4–Ln2(MoO4)3 systems where Ln = Nd, Sm, Eu, and Gd, have been studied by vibrational spectroscopy, X-ray powder diffraction, and differential thermal analysis. Triple molybdates KCaLn(MoO4)3 (Ln = Nd, Sm, Eu, and Gd) have been synthesized; they have a scheelite-derivative structure, monoclinic crystal system (space group P21/n). Their unit cell parameters have been determined, and IR and Raman spectra characterized.

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Authors and Affiliations

  1. Baikal Institute for Nature Management, Siberian Branch, Russian Academy of Sciences, Ulan-Ude, 670047, Russia

    N. M. Kozhevnikova

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  1. N. M. Kozhevnikova
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Correspondence to N. M. Kozhevnikova.

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Original Russian Text © N.M. Kozhevnikova, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 2, pp. 147–151.

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Kozhevnikova, N.M. Scheelite-Related Triple Molybdates KCaLn(MoO4)3 in K2MoO4–CaMoO4–Ln2(MoO4)3 (Ln = Nd, Sm, Eu, Gd) Systems: Synthesis and Characterization. Russ. J. Inorg. Chem. 63, 157–161 (2018). https://doi.org/10.1134/S0036023618020146

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  • DOI: https://doi.org/10.1134/S0036023618020146

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