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Extraction Properties of Oligoethylene Glycol Bis[(2-Diphenylphosphinylmethyl-4-methyl)phenyl] Ethers

  • Physical Chemistry of Solutions
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Abstract

Extraction of Ln(III), Sc(III), Ga(III), and Re(VII) ions by solutions of phosphorylated monopodands having [ortho-(diphenylphosphinylmethyl)-para-methyl]phenyl terminal groups, 2-Ph2P(O)CH2(4-Me)C6H3(OCH2CH2) n OC6H3(Me-4)CH2P(O)Ph2-2 (n = 1–5), in organic solvents has been studied. The stoichiometries of extractable complexes were determined. The effect of the aqueous phase, organic solvent, and phosphorylated podand structure on the efficacy of metal-ion recovery into organic phase has been considered.

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Authors and Affiliations

  1. Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    A. N. Turanov

  2. Institute of Microelectronic Technologies and High-Purity Materials, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. K. Karandashev

  3. National Research and Technology University MISiS, Moscow, 119991, Russia

    V. K. Karandashev

  4. State Research Institute of Chemicals and High-Purity Compounds (IREA), Moscow, 107076, Russia

    N. A. Bondarenko

Authors
  1. A. N. Turanov
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  2. V. K. Karandashev
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  3. N. A. Bondarenko
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Correspondence to A. N. Turanov.

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Original Russian Text © A.N. Turanov, V.K. Karandashev, N.A. Bondarenko, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 1, pp. 118–123.

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Turanov, A.N., Karandashev, V.K. & Bondarenko, N.A. Extraction Properties of Oligoethylene Glycol Bis[(2-Diphenylphosphinylmethyl-4-methyl)phenyl] Ethers. Russ. J. Inorg. Chem. 63, 128–133 (2018). https://doi.org/10.1134/S0036023618010205

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  • DOI: https://doi.org/10.1134/S0036023618010205

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