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Dioxomolybdenum(VI) Complexes with R1-Substituted Salicylidene Allylimines (Hl n ): Synthesis and Structure. Crystal Structure of [MoO2(L1)2] (R1 = H)

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Abstract

The synthesis and X-ray diffraction analysis of [MoO2(L1)2] has been performed. The molybdenum atom has a cis(Ooxo), cis(NL), trans(OL) octahedral coordination. The average bond lengths (Å): Mo–O(oxo), 1.691; Mo–N(L1), 2.351; Mo–O(L1), 1.954.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. S. Sergienko & Yu. E. Gorbunova

  2. All-Russia Institute of Scientific and Technical Information, Russian Academy of Sciences, Moscow, 125190, Russia

    V. S. Sergienko

  3. Dal’ East Ukrainian National University, Lugansk, 91034, Ukraine

    V. L. Abramenko

Authors
  1. V. S. Sergienko
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  2. V. L. Abramenko
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  3. Yu. E. Gorbunova
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Correspondence to V. S. Sergienko.

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Original Russian Text © V.S. Sergienko, V.L. Abramenko, Yu.E. Gorbunova, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 1, pp. 32–38.

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Sergienko, V.S., Abramenko, V.L. & Gorbunova, Y.E. Dioxomolybdenum(VI) Complexes with R1-Substituted Salicylidene Allylimines (Hl n ): Synthesis and Structure. Crystal Structure of [MoO2(L1)2] (R1 = H). Russ. J. Inorg. Chem. 63, 28–33 (2018). https://doi.org/10.1134/S003602361801014X

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  • DOI: https://doi.org/10.1134/S003602361801014X

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