Skip to main content
SpringerLink
Log in

Bis(Thiosemicarbazide)Copper(II) 1,5-Naphthalenedisulfonate Complex [Cu(Тsc)2](1,5-Nds): Synthesis and Crystal and Molecular Structures

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The synthesis, analysis, and IR spectroscopic, thermogravimetric, and X-ray diffraction study of [Cu(Тsc)2](Nds) (I), where Тsc is thiosemicarbazide NH2NHС(=S)NH2, and 1,5-Nds2– is the doubly deprotonated 1,5-naphthalenedisulfoacid anion C10H6(SO3) 2–2 , have been performed. Crystal structure units in complex I are [Cu(Тsc)2]2+ centrosymmetric complex cations and (Nds)2– anions (including those in inversion centers). The copper atom is coordinated to the vertices of a square via the two sulfur and two nitrogen atoms of the two bidentate-chelate (S,N) ligands Тsc. Crystal structure units in complex I are linked together by a branched network of weak nonlinear N–Н···О hydrogen bonds with participation of donors (all the five independent hydrogen atoms of the two NH2 groups and NH group of the [Cu(Tsc)]2+ complex cation) and acceptors (all the three independent oxygen atoms of the sulfato group of the 1,5-Nds2– anion).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Cai, Coord. Chem. Rev. 248, 1061 (2004).

    Article  CAS  Google Scholar 

  2. J. Cai, C.-H. Chen, Ch.-Z. Liao, et al., J. Chem. Soc., Dalton Trans., No. 7, 1137 (2001).

    Article  Google Scholar 

  3. G. G. Sadikov, A. S. Antsyshkina, T. V. Koksharova, et al., Crystallogr. Repts 57, 528 (2012).

    Article  CAS  Google Scholar 

  4. A. S. Antsyshkina, G. G. Sadikov, T. V. Koksharova, et al., Russ. J. Inorg. Chem. 57, 508 (2012).

    Article  CAS  Google Scholar 

  5. A. S. Antsyshkina, G. G. Sadikov, T. V. Koksharova, et al., Russ. J. Inorg. Chem. 57, 169 (2012).

    Article  CAS  Google Scholar 

  6. G. M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2008).

    Article  CAS  Google Scholar 

  7. F. H. Allen, Acta Crystallogr., Sect. B 58, 380 (2002).

    Article  Google Scholar 

  8. A. C. Villa, A. G. Manfredotti, and C. Guastini, Cryst. Struct. Commun. 1, 125 (1972).

    Google Scholar 

  9. V. Chernya, I. G. Filippova, A. Gulya, et al., Koord. Khim. 21, 370 (2005).

    Google Scholar 

  10. A. C. Villa, A. G. Manfredotti, and C. Guastini, Cryst. Struct. Commun. 1, 207 (1972).

    Google Scholar 

  11. Chao Quing, Li Cun, Zhou Jingui, et al., Kexue Tongbao (Chin. Sci. Bull.) 32, 321 (1987).

    Google Scholar 

  12. D. Chattopadhyay, S. K. Majimbar, P. Love, et al., J. Chem. Soc., Dalton Trans., No. 8, 2121 (1991).

    Article  Google Scholar 

  13. L. Jia, S. Ma, and D. Li, Acta Crystallogr., Sect. E 64, m796 (2008).

    Article  Google Scholar 

  14. R. Nimthong, N. Pakawatchai, and Y. Wattanakamjana, Acta Crystallogr., Sect. E 69, m244 (2013).

    Article  Google Scholar 

  15. L. Jia, S. Ma, and D. Li, Acta Crystallogr., Sect. E 64, m820 (2008).

    Article  Google Scholar 

  16. B. Singh, R. Singh, R. V. Chaudhary, and K. P. Thakur, Indian J. Chem. 11, 174 (1973).

    CAS  Google Scholar 

  17. J. Cai, C.-H. Chen, X.-L. Feng, et al., J. Chem. Soc., Dalton Trans., No. 16, P. 2370 (2001).

    Article  Google Scholar 

  18. J. Perles, N. Snejko, M. Iglesias, et al., J. Mater. Chem. 19, 6504 (2009).

    Article  CAS  Google Scholar 

  19. D. Sun, N. Zhang, Z.-H. Wei, et al., J. Mol. Struct. 981, 80 (2010).

    Article  CAS  Google Scholar 

  20. D. Sun, F.-J. Liu, H.-J. Hao, et al., Cryst. Eng. Commun. 13, 5661 (2011).

    Article  CAS  Google Scholar 

  21. S. Wang, R. Zhang, J. Wang, et al., Chem. Res. Chin. Univ. 30, 9 (2014).

    Article  Google Scholar 

  22. D. T. Tran, N. A. Chernova, D. Chu, et al., Cryst. Growth Des. 10, 874 (2010).

    Article  CAS  Google Scholar 

  23. T. V. Koksharova, Russ. J. Gen. Chem. 84, 1573 (2014).

    Article  CAS  Google Scholar 

  24. T. V. Koksharova, Russ. J. Gen. Chem. 85, 111 (2015).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. S. Sergienko, M. D. Surazhskaya & Yu. N. Mikhailov

  2. All-Russia Institute of Scientific and Technical Information, Russian Academy of Sciences, Moscow, 125190, Russia

    V. S. Sergienko

  3. Mechnikov National University, Odessa, 65082, Ukraine

    T. V. Koksharova & T. S. Skakun

Authors
  1. V. S. Sergienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. V. Koksharova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. D. Surazhskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. S. Skakun
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. N. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Sergienko.

Additional information

Original Russian Text © V.S. Sergienko, T.V. Koksharova, M.D. Surazhskaya, T.S. Skakun, Yu.N. Mikhailov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 1, pp. 26–31.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sergienko, V.S., Koksharova, T.V., Surazhskaya, M.D. et al. Bis(Thiosemicarbazide)Copper(II) 1,5-Naphthalenedisulfonate Complex [Cu(Тsc)2](1,5-Nds): Synthesis and Crystal and Molecular Structures. Russ. J. Inorg. Chem. 63, 22–27 (2018). https://doi.org/10.1134/S0036023618010138

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023618010138

Search

Navigation