Abstract
A new coordination compound having the formula [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4] (I), where HMPA is ((CH3)2N)3PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P21/n, a = 15.0360(3) Å, b = 15.1214(3) Å, c = 26.7529(7) Å, β = 100.6610(10)°, V = 5977.7(9) Å3, Z = 2, ρcalc = 1.442 g/cm3, and R1 = 0.0453 for 7344 reflections with Fo ≥ 4σ(Fo).
Similar content being viewed by others
References
S. Petricek, Acta Chim. Slov. 52, 398 (2005).
L. J. Radonovich, J. Inorg. Nucl. Chem. 35, 2745 (1973).
X. W. Zhang, Inorg. Chim. Acta 139, 103 (1987).
Z. Hou, Chem. Lett. 20, 265 (1991).
S. Petricek, Polyhedron 19, 199 (2000).
D. Barr, Angew. Chem., Int. Ed. Engl. 29, 285 (1990).
J. G. H. Preez, Inorg. Chim. Acta 26, 59 (1978).
S. Petricek, Z. Anorg. Allg. Chem. 631, 1947 (2005).
V. V. Skopenko, Yu. L. Zub, G. G. Sadikov, and M. A. Porai-Koshits, Ukr. Khim. Zh. 49, 675 (1983).
B. V. Bukvetskii, A. G. Mirochnik, P. A. Zhikhareva, and V. E. Karasev, Zh. Strukt. Khim. 51, 1200 (2010).
G. V. Tsintsadze, Z. O. Dzhavakhishvili, G. G. Aleksandrov, and Yu. T. Struchkov, Koord. Khim. 8, 367 (1982).
G. Tang, J. Zhang, and C. Zhang, Acta Crystallogr., Sect. E 64, m478 (2008).
J. Zhang, Acta Crystallogr., Sect. E 68, m843 (2012).
J. Zhang, Acta Crystallogr., Sect. E 67, m1365 (2011).
J. Zhang, Acta Crystallogr., Sect. E 66, m1479 (2010).
J. Zhang, Acta Crystallogr., Sect. E 68, m770 (2012).
J. Zhang, J. Qian, Y. Cao, and C. Zhang, Acta Crystallogr., Sect. E 63, m2386 (2007).
J. Zeng, G. Tang, and C. Wei, Acta Crystallogr., Sect. E 67, m1724 (2011).
H. Wei, J. Zhang, and C. Zhang, Acta Crystallogr., Sect. E 69, m43 (2013).
H. Wei, J. Zhang, and C. Zhang, Acta Crystallogr., Sect. E 66, m1657 (2010).
G. Tang, J. Zhang, C. Zhang, and L. Lu, Acta Crystallogr., Sect. E 64, m399 (2008).
J. Zhang, S. Meng, Y. Song, et al., New J. Chem. 35, 328 (2011).
V. V. Skopenko and A. A. Kapshuk, Koord. Khim. 11, 1202 (1985).
K. Asakura, Bull. Chem. Soc. Jpn. 74, 731 (2001).
A. Cabrera, Polyhedron 17, 193 (1998).
T. Imamoto, Chem. Lett. 24, 949 (1995).
T. Imamoto, Chem. Lett. 25, 875 (1996).
K. Mashima, Inorg. Chem. 35, 93 (1996).
Z. O. Dzhavakhishvili, Soobshch. Akad. Nauk Gruz. SSR 104, 637 (1981).
www.moscowuniversityclub.ru/home.asp?artId=9307.
G. M. Sheldrick, SADABS: Program for Empirical X-ray Absorption Correction (Bruker-Nonius, 1990–2004).
G. M. Sheldrick, Acta Crystallogr. 64, 112 (2008).
C. R. Groom, I. J. Bruno, and M. P. Lightfoot, and S. C. Ward, Crystallogr. 72, 171 (2016).
K., Nakanishi, Infrared Absorption Spectroscopy (Holden-Day, San Francisco, 1962).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (Interscience, New York, 1986).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Bobrovnikova, E.V. Peresypkina, A.V. Virovets, T.G. Cherkasova, E.S. Tatarinova, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 1, pp. 39–45.
Rights and permissions
About this article
Cite this article
Bobrovnikova, A.A., Peresypkina, E.V., Virovets, A.V. et al. Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III). Russ. J. Inorg. Chem. 63, 34–39 (2018). https://doi.org/10.1134/S0036023618010047
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023618010047