Skip to main content
Log in

Electrochemical synthesis and structure of 2-amino-1-ethylbenzimidazole adducts of copper, cobalt, and zinc chelates in the N,N,S ligand environment

  • Physical Methods of Investigation
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

2-Amino-1-ethylbenzimidazole (L1) adducts with copper(II), cobalt(II), and zinc(II) chelates of N,N,S tridentate tosylamino-functionalized mercaptopyrazole-containing Schiff base (H2L), resulting from condensation of 2-tosylaminoaniline with 1-phenyl-3-methyl-4-formylpyrazole-5-thiol, with the general formula [ML · L1] were obtained by electrochemical method. The structure and composition of the complexes were confirmed by the data of C, H, N elemental analysis, IR and 1H NMR spectroscopy, and magnetochemical and X-ray spectral measurements. The mononuclear structure of the copper(II) adduct with coordination bond located on the pyridine type endocyclic nitrogen atom of 2-amino-1-ethylbenzimidazole was proved by X-ray diffraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. P. Cassoux, L. Valade, and P.-L. Fabre, Comprehensive Coordination Chemistry II, Ed. by A. B. P. Lever, 200, vol. 1, p. 761.

  2. A. Rodriguez and J. A. Garcia-Vazquez, Coord. Chem. Rev. 303, 42 (2015).

    Article  CAS  Google Scholar 

  3. M. Bernal, J. A. Garcia-Vazquez, J. Romero, et al., Inorg. Chim. Acta 295, 39 (1999).

    Article  CAS  Google Scholar 

  4. A. D. Garnovskii, A. S. Burlov, D. A. Garnovskii, et al., Polyhedron 18, 1985 (1999).

    Article  Google Scholar 

  5. J. Sanmartin, F. Novio, A. M. Garcia-Deibe, et al., Eur. J. Inorg. Chem., No. 10, 1719 (2008).

    Article  Google Scholar 

  6. A. S. Antsyshkina, G. G. Sadikov, A. S. Burlov, et al., Russ. J. Inorg. Chem. 50, 346 (2005).

    Google Scholar 

  7. D. A. Garnovskii, A. Sousa, A. S. Antsyshkina, et al., Izv. Akad. Nauk, Ser. Khim. 45, 1988 (1996).

    Google Scholar 

  8. D. A. Garnovskii, M. F. C. Guedes Da Silva, M. N. Kopylovich, et al., Polyhedron 22, 1335 (2003).

    Article  CAS  Google Scholar 

  9. A. S. Antsyshkina, G. G. Sadikov, A. S. Burlov, et al., Koord. Khim. 26, 730 (2000).

    CAS  Google Scholar 

  10. L. De Luca, Curr. Med. Chem. 13, 1 (2006).

    Google Scholar 

  11. E. Buncel, I. Onyido, and J. Label, Compd. Radiopharm. 45, 91 (2002).

    Article  Google Scholar 

  12. S. J. Lippard and J. M. Berg, Principles of Bioinorganic Chemistry (University Science Books, Mill Valley, 1994).

    Google Scholar 

  13. Concepts and Models in Bioinorganic Chemistry, Ed. by H.-B. Kraatz and N. Metzler-Nolte (Wiley-VCH, Weinheim, 2006).

  14. P. Armo-Ochoa and F. Zamora, Coord. Chem. Rev. 276, 34 (2014).

    Article  Google Scholar 

  15. J. M. Matthews, F. E. Loughlin, and J. P. Mackay, Curr. Opin. Struct. Biol. 18, 484 (2008).

    Article  CAS  Google Scholar 

  16. D. A. Garnovskii, A. D. Garnovskii, A. P. Sadimenko, et al., Koord. Khim. 20, 17 (1994).

    Google Scholar 

  17. L.-A. de Jongh, C. E. Strasser, H. G. Raubenheimer, et al., Polyhedron 28, 3635 (2009).

    Article  CAS  Google Scholar 

  18. H. Kitamura, T. Ozawa, K. Jitsukawa, et al., Inorg. Chem. 39, 3924 (2000).

    Article  Google Scholar 

  19. D. A. Bashirov, T. S. Sukhikh, N. V. Kuratieva, et al., RSC Adv. 4, 28309 (2014).

    CAS  Google Scholar 

  20. E. V. Pakhmutova, A. E. Malkov, T. B. Mikhailova, et al., Russ. Chem. Bull. 52, 139 (2003).

    Article  CAS  Google Scholar 

  21. T. W. Stringfield and R. E. Sheperd, Inorg. Chem. Commun. 4, 760 (2001).

    Article  CAS  Google Scholar 

  22. I. A. Morkan, G. Kutalmis, and S. Özkar, J. Organomet. Chem. 689, 2319 (2004).

    Article  CAS  Google Scholar 

  23. C. M. Stanfest-Hayser, K. Mereiter, R. Schmid, and K. Kirchner, Dalton Trans., 2329 (2003).

    Google Scholar 

  24. I. Ya. Kvitko, Zh. Org. Khim. 5, 1685 (1969).

    CAS  Google Scholar 

  25. W. U. Malick and T. S. Sharma, J. Ind. Chem. Soc. 47, 167 (1970).

    Google Scholar 

  26. D. G. Tuck, Pure Appl. Chem. 51, 2005 (1979).

    Article  CAS  Google Scholar 

  27. A. A. Chernyshov, A. A. Veligzhanin, and Y. V. Zubavichus, Nucl. Instr. Meth. Phys. Res. A 603, 95 (2009).

    Article  CAS  Google Scholar 

  28. D. I. Kochubei, Yu. A. Babanov, K. I. Zamaraev, et al., X-ray Spectral Method of Studying Amorphous Solids: EXAFS Spectroscopy (Nauka. Sib. Otd., Novosibirsk, 1988) [in Russian].

    Google Scholar 

  29. M. Newville, J. Synchrotron Rad. 8, 96 (2001).

    Article  CAS  Google Scholar 

  30. S. I. Zabinsky, J. J. Rehr, A. Ankudinov, et al., Phys. Rev. B 52, 2995 (1995).

    Article  CAS  Google Scholar 

  31. CrysAlisPro, Agilent Technologies, Version 1.171.36.32.

  32. G. M. Sheldrick, Program for the Refinement of Crystal Structure, Univ. of Göttingen, Göttingen, 1997.

    Google Scholar 

  33. L. N. Kurkovskaya, N. N. Shapet’ko, I. Ya. Kvitko, et al., Zh. Org. Khim. 10, 2210 (1974).

    CAS  Google Scholar 

  34. D. A. Garnovskii, S. I. Levchenkov, N. I. Makarova, et al., Russ. J. Coord. Chem. (in press).

  35. A. S. Antsyshkina, G. G. Sadikov, A. S. Burlov, et al., Koord. Khim. 26, 730 (2000).

    CAS  Google Scholar 

  36. D. A. Garnovskii, G. G. Sadikov, A. S. Antsyshkina, et al., Crystallogr. Rep. 48, 426 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. A. Garnovskii.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Garnovskii, D.A., Aleksandrov, G.G., Makarova, N.I. et al. Electrochemical synthesis and structure of 2-amino-1-ethylbenzimidazole adducts of copper, cobalt, and zinc chelates in the N,N,S ligand environment. Russ. J. Inorg. Chem. 62, 1077–1084 (2017). https://doi.org/10.1134/S0036023617080071

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023617080071

Keywords

Navigation