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Copper(II), nickel(II), and zinc(II) complexes with o-tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone

  • Coordination Compounds
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Abstract

o-Tosylaminobenzaldehyde dimethylpyrimidyl hydrazone and its copper(II), nickel(II), and zinc(II) complexesare synthesized and studied. According to the X-ray diffraction data, the zinc(II) complex has the structure of a tetragonal pyramid with the N3O donor ligand environment. According to EPR and magnetochemistry data, the copper(II) complex has a similar structure of the chelate core. In the nickel(II) complex, the solvent molecule completes the coordination core to an octahedron.

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References

  1. E. V. Bogatyreva, V. A. Kogan, V. V. Lukov, and V. A. Lokshin, Zh. Neorg. Khim. 35, 2010 (1990).

    CAS  Google Scholar 

  2. Yu. P. Tupolova, V. V. Lukov, V. A. Kogan, and L. D. Popov, Koord. Khim. 33, 310 (2007).

    Article  Google Scholar 

  3. V. V. Lukov, G. G. Aleksandrov, V. A. Dontsova, et al., Koord. Khim. 31, 770 (2005).

    Google Scholar 

  4. L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, and V. A. Kogan, Zh. Obshch. Khim. 77, 1203 (2007).

    Google Scholar 

  5. T. A. Yusman, S. G. Kochin, V. V. Lukov, et al., Zh. Neorg. Khim., No. 5, 863 (1993).

    Google Scholar 

  6. M. Calinescu, E. Ion, and A.-M. Stadler, Rev. Roum. Chim. 53, 903 (2008).

    CAS  Google Scholar 

  7. S. Gupta, S. Pal, A. K. Barik, et al., Polyhedron 27, 2519 (2008).

    Article  CAS  Google Scholar 

  8. S. Ray, S. Jana, A. Jana, et al., Polyhedron 46, 74 (2012).

    Article  CAS  Google Scholar 

  9. S. Ray, S. Konar, A. Jana, et al., Polyhedron 50, 51 (2013).

    Article  CAS  Google Scholar 

  10. S. Ray, S. Konar, A. Jana, et al., J. Mol. Struct. 1058, 213 (2014).

    Article  CAS  Google Scholar 

  11. S. Konar, J. Mol. Struct. 1092, 34 (2015).

    Article  CAS  Google Scholar 

  12. A. I. Uraev, I. S. Vasilchenko, V. N. Ikorskii, et al., Mendeleev Commun. 15, 133 (2005).

    Article  Google Scholar 

  13. A. S. Burlov, Yu. V. Koshchienko, V. N. Ikorskii et al., Russ. J. Inorg. Chem. 51, 1065 (2006).

    Article  Google Scholar 

  14. A. D. Garnovskii, V. N. Ikorskii, A. I. Uraev, et al., J. Coord. Chem. 60, 1493 (2007).

    Article  CAS  Google Scholar 

  15. A. S. Burlov, V. N. Ikorskii, S. A. Nikolaevskii, et al., Russ. J. Inorg. Chem. 53, 1566 (2008).

    Article  Google Scholar 

  16. L. D. Popov, I. N. Shcherbakov, S. I. Levchenkov, et al., Koord. Khim. 37, 483 (2011).

    Article  CAS  Google Scholar 

  17. S. I. Levchenkov, L. D. Popov, N. N. Efimov, et al., Russ. J. Inorg. Chem. 60, 1129 (2015).

    Article  CAS  Google Scholar 

  18. L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, et al., Koord. Khim. 39, 259 (2013).

    Google Scholar 

  19. J. S. Casas, E. E. Castellans, M. D. Louce, et al., Biochemistry 11, 1858 (2006).

    Google Scholar 

  20. U. Koch, B. Attenni, S. Malancona, et al., Med. J. Chem 49, 1693 (2006).

    Article  CAS  Google Scholar 

  21. A. T. Soldatenkov, M. N. Kolyadina, and I. V. Shendrik, The Fundamentals of Organic Chemistry of Drugs (Khimiya, Moscow, 2001) [in Russian].

    Google Scholar 

  22. M. D. Mashkovskii, Medicaments (Novaya Volna, Moscow, 1216) [in Russian].

    Google Scholar 

  23. G. M. Kosolapoff and C. H. Roy, Org. Chem. 26, 1895 (1961).

    Article  CAS  Google Scholar 

  24. J. Inczedy, Analytical Applications of Complex Equilibria (Akademiai Kiado, Budapest, 1976).

    Google Scholar 

  25. Yu. V. Rakitin, G. M. Larin, and V. V. Minin, The Interpretation of EPR Spectra of Coordination Compounds (Nauka, Moscow, 1993) [in Russian].

    Google Scholar 

  26. Ya. S. Lebedev and V. I. Muromtsev, EPR and the Relaxation of Stabilized Radicals (Khimiya, Moscow, 1972) [in Russian].

    Google Scholar 

  27. G. M. Sheldrick, SHELXTL (Bruker, 2000).

    Google Scholar 

  28. D. Martin, M. Rouffet, and S. M. Cohen, Inorg. Chem. 49, 10226 (2010).

    Article  CAS  Google Scholar 

  29. Yu. V. Rakitin and V. T. Kalinnikov, Advanced Magnetochemistry (Nauka, St. Petersburg, 1994) [in Russian].

    Google Scholar 

Download references

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Correspondence to L. D. Popov.

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Original Russian Text © L.D. Popov, V.V. Tkachev, Yu.P. Tupolova, S.A. Borodkin, G.V. Shilov, E.A. Ugolkova, O.I. Askalepova, A.S. Burlov, V.V. Lukov, I.N. Shcherbakov, S.I. Levchenkov, V.V. Minin, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 7, pp. 912–919.

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Popov, L.D., Tkachev, V.V., Tupolova, Y.P. et al. Copper(II), nickel(II), and zinc(II) complexes with o-tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone. Russ. J. Inorg. Chem. 62, 893–899 (2017). https://doi.org/10.1134/S003602361707018X

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  • DOI: https://doi.org/10.1134/S003602361707018X

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